View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

M J  Paterson; N P  Chatterton; G S  McGrady; Martin Paterson

doi:10.1039/b412371a

View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

M J Paterson
, N P Chatterton
, G S McGrady
, Martin Paterson

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

141 Downloads (Pure)

Abstract

The model complex [Cp(CO)(2)Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn-Teller distortion which brings an equatorial Si-H moiety into contact with the Mn centre.

Original language	English
Pages (from-to)	1434-1436
Number of pages	3
Journal	New Journal of Chemistry
Volume	28
Issue number	12
DOIs	https://doi.org/10.1039/b412371a
Publication status	Published - 2004

Keywords

HYDRIDES
LIGANDS
BONDS

Access to Document

10.1039/b412371a

PJT Silane publishedFinal published version, 556 KB

Cite this

@article{1855193d969c4aac8b0f44be3df1cb98,

title = "View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes",

abstract = "The model complex [Cp(CO)(2)Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn-Teller distortion which brings an equatorial Si-H moiety into contact with the Mn centre.",

keywords = "HYDRIDES, LIGANDS, BONDS",

author = "Paterson, \{M J\} and Chatterton, \{N P\} and McGrady, \{G S\} and Martin Paterson",

year = "2004",

doi = "10.1039/b412371a",

language = "English",

volume = "28",

pages = "1434--1436",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

AU - Paterson, M J

AU - Chatterton, N P

AU - McGrady, G S

AU - Paterson, Martin

PY - 2004

Y1 - 2004

N2 - The model complex [Cp(CO)(2)Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn-Teller distortion which brings an equatorial Si-H moiety into contact with the Mn centre.

AB - The model complex [Cp(CO)(2)Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn-Teller distortion which brings an equatorial Si-H moiety into contact with the Mn centre.

KW - HYDRIDES

KW - LIGANDS

KW - BONDS

U2 - 10.1039/b412371a

DO - 10.1039/b412371a

M3 - Article

SN - 1144-0546

VL - 28

SP - 1434

EP - 1436

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 12

ER -

View from the bridge: a pseudo-Jahn-Teller approach to transition metal hydrosilane complexes

Abstract

Keywords

Access to Document

Fingerprint

Cite this