Vibrational relaxation of NCO(X̃) by rare gases, and rate constant measurement of the NCO + NO reaction

G. Hancock; K. G. Mckendrick

doi:10.1016/S0009-2614(86)80239-1

Vibrational relaxation of NCO(X̃) by rare gases, and rate constant measurement of the NCO + NO reaction

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Abstract

Vibrational relaxation of the v₂ mode of NCO(X̃) by rare gases takes place at rates which are in the order Ne < He ≈ Ar < Kr. The bimolecular rate constant for the NCO + NO reaction is (3.4±0.3)×10^-11 cm³ molecule^-1 s^-1 at 295 K.

Original language	English
Pages (from-to)	125-129
Number of pages	5
Journal	Chemical Physics Letters
Volume	127
Issue number	2
DOIs	https://doi.org/10.1016/S0009-2614(86)80239-1
Publication status	Published - 6 Jun 1986

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/S0009-2614(86)80239-1

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Hancock, G., & Mckendrick, K. G. (1986). Vibrational relaxation of NCO(X̃) by rare gases, and rate constant measurement of the NCO + NO reaction. Chemical Physics Letters, 127(2), 125-129. https://doi.org/10.1016/S0009-2614(86)80239-1

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abstract = "Vibrational relaxation of the v2 mode of NCO({\~X}) by rare gases takes place at rates which are in the order Ne < He ≈ Ar < Kr. The bimolecular rate constant for the NCO + NO reaction is (3.4±0.3)×10-11 cm3 molecule-1 s-1 at 295 K.",

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