Vacuum ultraviolet spectrum of dinitrogen pentoxide

Bruce A. Osborne, George Marston, L. Kaminski, N. C. Jones, J. M. Gingell, Nigel Mason, Isobel C. Walker, J. Delwiche, M. J. Hubin-Franskin

Research output: Contribution to journalArticle

Abstract

Absolute photoabsorption cross-sections at 195 + 3 K are reported for dinitrogen pentoxide, N2O5, between 150 and 240 nm. The spectrum consists of a broad intense band with a maximum at 160 nm. The lack of sharp features indicates that excitation of N2O5 results in dissociation over the whole of the spectral range studied. At wavelengths above 200 nm, our results are up to 30% smaller than the current NASA recommendation, but are in generally good agreement with a more recent measurement. Below 200 nm, there are no reported data with which to compare our work. © 1999 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)67-74
Number of pages8
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume64
Issue number1
Publication statusPublished - Jan 2000

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ultraviolet spectra
photoabsorption
recommendations
dissociation
broadband
vacuum
cross sections
wavelengths
excitation

Cite this

Osborne, B. A., Marston, G., Kaminski, L., Jones, N. C., Gingell, J. M., Mason, N., ... Hubin-Franskin, M. J. (2000). Vacuum ultraviolet spectrum of dinitrogen pentoxide. Journal of Quantitative Spectroscopy and Radiative Transfer, 64(1), 67-74.
Osborne, Bruce A. ; Marston, George ; Kaminski, L. ; Jones, N. C. ; Gingell, J. M. ; Mason, Nigel ; Walker, Isobel C. ; Delwiche, J. ; Hubin-Franskin, M. J. / Vacuum ultraviolet spectrum of dinitrogen pentoxide. In: Journal of Quantitative Spectroscopy and Radiative Transfer. 2000 ; Vol. 64, No. 1. pp. 67-74.
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Osborne, BA, Marston, G, Kaminski, L, Jones, NC, Gingell, JM, Mason, N, Walker, IC, Delwiche, J & Hubin-Franskin, MJ 2000, 'Vacuum ultraviolet spectrum of dinitrogen pentoxide', Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 64, no. 1, pp. 67-74.

Vacuum ultraviolet spectrum of dinitrogen pentoxide. / Osborne, Bruce A.; Marston, George; Kaminski, L.; Jones, N. C.; Gingell, J. M.; Mason, Nigel; Walker, Isobel C.; Delwiche, J.; Hubin-Franskin, M. J.

In: Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 64, No. 1, 01.2000, p. 67-74.

Research output: Contribution to journalArticle

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AU - Osborne, Bruce A.

AU - Marston, George

AU - Kaminski, L.

AU - Jones, N. C.

AU - Gingell, J. M.

AU - Mason, Nigel

AU - Walker, Isobel C.

AU - Delwiche, J.

AU - Hubin-Franskin, M. J.

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AB - Absolute photoabsorption cross-sections at 195 + 3 K are reported for dinitrogen pentoxide, N2O5, between 150 and 240 nm. The spectrum consists of a broad intense band with a maximum at 160 nm. The lack of sharp features indicates that excitation of N2O5 results in dissociation over the whole of the spectral range studied. At wavelengths above 200 nm, our results are up to 30% smaller than the current NASA recommendation, but are in generally good agreement with a more recent measurement. Below 200 nm, there are no reported data with which to compare our work. © 1999 Elsevier Science Ltd. All rights reserved.

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Osborne BA, Marston G, Kaminski L, Jones NC, Gingell JM, Mason N et al. Vacuum ultraviolet spectrum of dinitrogen pentoxide. Journal of Quantitative Spectroscopy and Radiative Transfer. 2000 Jan;64(1):67-74.