Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

Stephen M Mansell; Fanny Bonnet; Marc Visseaux; Polly L. Arnold

doi:10.1039/c3dt50131k

Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

Stephen M Mansell
, Fanny Bonnet^*
, Marc Visseaux
, Polly L. Arnold

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N '')(2)U{kappa(2)-N(SiMe3)-SiMe2CH2BBN-H} and U{kappa(2)-N(SiMe3)SiMe2CH2BBN-H}(2), and their activity as pre-catalysts for the polymerisation of isoprene are described.

Original language	English
Pages (from-to)	9033-9039
Number of pages	7
Journal	Dalton Transactions
Volume	42
Issue number	25
DOIs	https://doi.org/10.1039/c3dt50131k
Publication status	Published - 2013

Keywords

HYDROGEN-DEUTERIUM EXCHANGE
ISOPRENE POLYMERIZATION
STEREOSPECIFIC POLYMERIZATION
COMPLEXES
CHEMISTRY
LIGANDS
CRYSTAL
HYDRIDE
ACTIVATION
INSERTION

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10.1039/c3dt50131k

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title = "Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts",

abstract = "The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N '')(2)U\{kappa(2)-N(SiMe3)-SiMe2CH2BBN-H\} and U\{kappa(2)-N(SiMe3)SiMe2CH2BBN-H\}(2), and their activity as pre-catalysts for the polymerisation of isoprene are described.",

keywords = "HYDROGEN-DEUTERIUM EXCHANGE, ISOPRENE POLYMERIZATION, STEREOSPECIFIC POLYMERIZATION, COMPLEXES, CHEMISTRY, LIGANDS, CRYSTAL, HYDRIDE, ACTIVATION, INSERTION",

author = "Mansell, \{Stephen M\} and Fanny Bonnet and Marc Visseaux and Arnold, \{Polly L.\}",

year = "2013",

doi = "10.1039/c3dt50131k",

language = "English",

volume = "42",

pages = "9033--9039",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "25",

}

TY - JOUR

T1 - Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

AU - Mansell, Stephen M

AU - Bonnet, Fanny

AU - Visseaux, Marc

AU - Arnold, Polly L.

PY - 2013

Y1 - 2013

N2 - The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N '')(2)U{kappa(2)-N(SiMe3)-SiMe2CH2BBN-H} and U{kappa(2)-N(SiMe3)SiMe2CH2BBN-H}(2), and their activity as pre-catalysts for the polymerisation of isoprene are described.

AB - The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N '')(2)U{kappa(2)-N(SiMe3)-SiMe2CH2BBN-H} and U{kappa(2)-N(SiMe3)SiMe2CH2BBN-H}(2), and their activity as pre-catalysts for the polymerisation of isoprene are described.

KW - HYDROGEN-DEUTERIUM EXCHANGE

KW - ISOPRENE POLYMERIZATION

KW - STEREOSPECIFIC POLYMERIZATION

KW - COMPLEXES

KW - CHEMISTRY

KW - LIGANDS

KW - CRYSTAL

KW - HYDRIDE

KW - ACTIVATION

KW - INSERTION

U2 - 10.1039/c3dt50131k

DO - 10.1039/c3dt50131k

M3 - Article

C2 - 23571673

SN - 1477-9226

VL - 42

SP - 9033

EP - 9039

JO - Dalton Transactions

JF - Dalton Transactions

IS - 25

ER -

Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

Abstract

Keywords

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