Unsymmetrically substituted butenynyl-iron(ii) complexes

Leslie D. Field; Alison M. Magill; Stuart R. Pike; Anthony J. Turnbull; Scott J. Dalgarno; Peter Turner; Anthony C. Willis

doi:10.1002/ejic.201000281

Unsymmetrically substituted butenynyl-iron(ii) complexes

Leslie D. Field, Alison M. Magill, Stuart R. Pike, Anthony J. Turnbull, Scott J. Dalgarno, Peter Turner, Anthony C. Willis

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The preparation and characterisation of iron(II) complexes bearing unsymmetrically 1,4-disubstituted n?³-butenynyl ligands, cis-[Fe(C(C=CR)=C(H)R')(dmpe)₂][PF₆] (e.g. R = tBu, R' = Ph 2e; R = Ph, R' = tBu 2e') are reported. The complexes were obtained as a mixture by protonation and rearrangement of the bis(acetylido)iron(II) complex trans-Fe(CCPh)(CCtBu)(dmpe)₂. The complexes 2e and 2e' were separated by crystallisation and were both characterised, crystallographically. In addition, a number of complexes with symmetrically 1,4-disubstituted butenynyl ligands cis[Fe(C(C=CR)=C(H)R)(dmpe)₂][PF₆] (R = p-C₆H₄-OMe 2a; pC₆H₄-Me 2b, C ₆H₃-3,5-(CF₃)₂ 2c; 1-adamantyl 2d) were synthesized by protonation and rearrangement of the corresponding bis(acetylido)iron(II) complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	2406-2414
Number of pages	9
Journal	European Journal of Inorganic Chemistry
Issue number	16
DOIs	https://doi.org/10.1002/ejic.201000281
Publication status	Published - Jun 2010

Keywords

Enynes
Iron
Phosphane ligands
Rearrangement

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10.1002/ejic.201000281

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@article{ebb04731be7446e99ad809e73e0c41a6,

title = "Unsymmetrically substituted butenynyl-iron(ii) complexes",

abstract = "The preparation and characterisation of iron(II) complexes bearing unsymmetrically 1,4-disubstituted n?3-butenynyl ligands, cis-[Fe(C(C=CR)=C(H)R')(dmpe)2][PF6] (e.g. R = tBu, R' = Ph 2e; R = Ph, R' = tBu 2e') are reported. The complexes were obtained as a mixture by protonation and rearrangement of the bis(acetylido)iron(II) complex trans-Fe(CCPh)(CCtBu)(dmpe)2. The complexes 2e and 2e' were separated by crystallisation and were both characterised, crystallographically. In addition, a number of complexes with symmetrically 1,4-disubstituted butenynyl ligands cis[Fe(C(C=CR)=C(H)R)(dmpe)2][PF6] (R = p-C6H4-OMe 2a; pC6H4-Me 2b, C 6H3-3,5-(CF3)2 2c; 1-adamantyl 2d) were synthesized by protonation and rearrangement of the corresponding bis(acetylido)iron(II) complexes. {\textcopyright} 2010 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

keywords = "Enynes, Iron, Phosphane ligands, Rearrangement",

author = "Field, \{Leslie D.\} and Magill, \{Alison M.\} and Pike, \{Stuart R.\} and Turnbull, \{Anthony J.\} and Dalgarno, \{Scott J.\} and Peter Turner and Willis, \{Anthony C.\}",

year = "2010",

month = jun,

doi = "10.1002/ejic.201000281",

language = "English",

pages = "2406--2414",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "16",

}

TY - JOUR

T1 - Unsymmetrically substituted butenynyl-iron(ii) complexes

AU - Field, Leslie D.

AU - Magill, Alison M.

AU - Pike, Stuart R.

AU - Turnbull, Anthony J.

AU - Dalgarno, Scott J.

AU - Turner, Peter

AU - Willis, Anthony C.

PY - 2010/6

Y1 - 2010/6

N2 - The preparation and characterisation of iron(II) complexes bearing unsymmetrically 1,4-disubstituted n?3-butenynyl ligands, cis-[Fe(C(C=CR)=C(H)R')(dmpe)2][PF6] (e.g. R = tBu, R' = Ph 2e; R = Ph, R' = tBu 2e') are reported. The complexes were obtained as a mixture by protonation and rearrangement of the bis(acetylido)iron(II) complex trans-Fe(CCPh)(CCtBu)(dmpe)2. The complexes 2e and 2e' were separated by crystallisation and were both characterised, crystallographically. In addition, a number of complexes with symmetrically 1,4-disubstituted butenynyl ligands cis[Fe(C(C=CR)=C(H)R)(dmpe)2][PF6] (R = p-C6H4-OMe 2a; pC6H4-Me 2b, C 6H3-3,5-(CF3)2 2c; 1-adamantyl 2d) were synthesized by protonation and rearrangement of the corresponding bis(acetylido)iron(II) complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - The preparation and characterisation of iron(II) complexes bearing unsymmetrically 1,4-disubstituted n?3-butenynyl ligands, cis-[Fe(C(C=CR)=C(H)R')(dmpe)2][PF6] (e.g. R = tBu, R' = Ph 2e; R = Ph, R' = tBu 2e') are reported. The complexes were obtained as a mixture by protonation and rearrangement of the bis(acetylido)iron(II) complex trans-Fe(CCPh)(CCtBu)(dmpe)2. The complexes 2e and 2e' were separated by crystallisation and were both characterised, crystallographically. In addition, a number of complexes with symmetrically 1,4-disubstituted butenynyl ligands cis[Fe(C(C=CR)=C(H)R)(dmpe)2][PF6] (R = p-C6H4-OMe 2a; pC6H4-Me 2b, C 6H3-3,5-(CF3)2 2c; 1-adamantyl 2d) were synthesized by protonation and rearrangement of the corresponding bis(acetylido)iron(II) complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - Enynes

KW - Iron

KW - Phosphane ligands

KW - Rearrangement

UR - https://www.scopus.com/pages/publications/77953110063

U2 - 10.1002/ejic.201000281

DO - 10.1002/ejic.201000281

M3 - Article

SN - 1434-1948

SP - 2406

EP - 2414

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 16

ER -

Unsymmetrically substituted butenynyl-iron(ii) complexes

Abstract

Keywords

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