Unsaturated heterobinuclear complexes of rhodium with molybdenum, tungsten, and manganese. X-ray crystal structure of [MoRh(μ-CO)2(CO) (PPh3)(η-C5H5)]

Laurence Carlton, W. Edward Lindsell, Kevin J. McCullough, Peter N. Preston

Research output: Contribution to journalArticle

Abstract

The new, related bimetallic complexes [MRh(µ-CO)2(CO) (PPh3)2(?-C5H5)] (M = Mo and W) and [MnRh(µ-CO)2(CO)2(PPh3)3] have been characterized and some chemical properties examined; the crystal structure of the molybdenum-rhodium complex, determined by X-ray crystallography, reveals a short multiple Mo-Rh bond.

Original languageEnglish
Pages (from-to)1001-1003
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
Publication statusPublished - 1982

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