Two new octahedral Cd(II) complexes [Cd(L)2] and {[Cd(LH) 2(SCN)2]H2O} [L = C6H 5C(OH)NN = C(CH3)C5H4N]: Synthesis and structural studies

Soma Sen, Pritha Talukder, Georgina Rosair, Samiran Mitra

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Two new octahedral Cd(II) complexes [Cd(L)2] (1) and {[Cd(LH)2(SCN)2]H2O} (2) [where LH = C 14H13N3O] are synthesized using a tridentate hydrazone ligand (LH) and they are characterized by elemental analysis, IR spectra, NMR spectra, thermal studies and finally the structures have been determined by single crystal X-ray diffraction. Complex 1 crystallizes in monoclinic system, space group C2lc with a = 22.565(6) Å, b = 10.252(3) Å, c = 12.187(4) Å, ß = 118.851(2)°, and Z = 4. Complex 2 also crystallizes in the monoclinic system, space group P21/c with a = 9.257(9)Å, b = 17.809(2)Å, c = 9.548(9)Å, ß = 107.439(4)°, and Z = 2. In 1 the ligand binds the Cd(II) ion in tridentate fashion, whereas in 2 it acts as a bidentate ligand. © 2005 Springer Science+Business Media, Inc.

Original languageEnglish
Pages (from-to)605-610
Number of pages6
JournalStructural Chemistry
Volume16
Issue number6
DOIs
Publication statusPublished - Dec 2005

Keywords

  • Cadmium(II)
  • Crystal structures
  • Hydrazone ligand

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