Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ1,5- dca)2(salicyh)2]n and {[Ni(μ1,5- dca)(TTA)](ClO4)}n (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies

Soma Sen; Pritha Talukder; Samiran Mitra; Georgina Rosair; Glenn Yap; Volker Gramlich; Jinkwon Kim; T. Matsushita; Cédric Desplanches; Jean Pascal Sutter

doi:10.1016/j.ica.2005.08.006

Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies

Soma Sen
, Pritha Talukder
, Samiran Mitra
, Georgina Rosair
, Glenn Yap
, Volker Gramlich
, Jinkwon Kim
, T. Matsushita
, Cédric Desplanches
, Jean Pascal Sutter

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Two new dicyanamide bridged complexes [Mn(µ_1,5-dca) ₂(salicyh)₂]_n (1) and {[Ni(µ_1,5- dca)(TTA)](ClO₄)}_n (2) (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine) have been synthesised and structurally characterised. Both the compounds 1 and 2 consist in 1-D coordination polymers. In 1 the manganese atoms are doubly bridged by µ_1,5-dca ligands, whereas in 2 the nickel atoms are bridged by a single µ_1,5-dca ligand. The magnetic measurements indicate that whereas intrachain interactions take place between the metal ions for compound 1 (J = -0.26 cm^-1), no evidence for any exchange coupling is found for compound 2. © 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	4534-4540
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	358
Issue number	15
DOIs	https://doi.org/10.1016/j.ica.2005.08.006
Publication status	Published - 1 Dec 2005

Keywords

Dicyanamide
Magnetic studies
Manganese(II), Nickel(II) complexes
Structural studies

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10.1016/j.ica.2005.08.006

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Sen, S., Talukder, P., Mitra, S., Rosair, G., Yap, G., Gramlich, V., Kim, J., Matsushita, T., Desplanches, C., & Sutter, J. P. (2005). Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies. Inorganica Chimica Acta, 358(15), 4534-4540. https://doi.org/10.1016/j.ica.2005.08.006

Sen, Soma ; Talukder, Pritha ; Mitra, Samiran et al. / Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine) : Synthesis, structures and magnetic studies. In: Inorganica Chimica Acta. 2005 ; Vol. 358, No. 15. pp. 4534-4540.

@article{175eab6f39ca42aea4b679cfbf72c043,

title = "Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ1,5- dca)2(salicyh)2]n and \{[Ni(μ1,5- dca)(TTA)](ClO4)\}n (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies",

abstract = "Two new dicyanamide bridged complexes [Mn(µ1,5-dca) 2(salicyh)2]n (1) and \{[Ni(µ1,5- dca)(TTA)](ClO4)\}n (2) (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine) have been synthesised and structurally characterised. Both the compounds 1 and 2 consist in 1-D coordination polymers. In 1 the manganese atoms are doubly bridged by µ1,5-dca ligands, whereas in 2 the nickel atoms are bridged by a single µ1,5-dca ligand. The magnetic measurements indicate that whereas intrachain interactions take place between the metal ions for compound 1 (J = -0.26 cm-1), no evidence for any exchange coupling is found for compound 2. {\textcopyright} 2005 Elsevier B.V. All rights reserved.",

keywords = "Dicyanamide, Magnetic studies, Manganese(II), Nickel(II) complexes, Structural studies",

author = "Soma Sen and Pritha Talukder and Samiran Mitra and Georgina Rosair and Glenn Yap and Volker Gramlich and Jinkwon Kim and T. Matsushita and C{\'e}dric Desplanches and Sutter, \{Jean Pascal\}",

year = "2005",

month = dec,

day = "1",

doi = "10.1016/j.ica.2005.08.006",

language = "English",

volume = "358",

pages = "4534--4540",

journal = "Inorganica Chimica Acta",

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Sen, S, Talukder, P, Mitra, S, Rosair, G, Yap, G, Gramlich, V, Kim, J, Matsushita, T, Desplanches, C & Sutter, JP 2005, 'Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies', Inorganica Chimica Acta, vol. 358, no. 15, pp. 4534-4540. https://doi.org/10.1016/j.ica.2005.08.006

Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies. / Sen, Soma; Talukder, Pritha; Mitra, Samiran et al.
In: Inorganica Chimica Acta, Vol. 358, No. 15, 01.12.2005, p. 4534-4540.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ1,5- dca)2(salicyh)2]n and {[Ni(μ1,5- dca)(TTA)](ClO4)}n (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine)

T2 - Synthesis, structures and magnetic studies

AU - Sen, Soma

AU - Talukder, Pritha

AU - Mitra, Samiran

AU - Rosair, Georgina

AU - Yap, Glenn

AU - Gramlich, Volker

AU - Kim, Jinkwon

AU - Matsushita, T.

AU - Desplanches, Cédric

AU - Sutter, Jean Pascal

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Two new dicyanamide bridged complexes [Mn(µ1,5-dca) 2(salicyh)2]n (1) and {[Ni(µ1,5- dca)(TTA)](ClO4)}n (2) (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine) have been synthesised and structurally characterised. Both the compounds 1 and 2 consist in 1-D coordination polymers. In 1 the manganese atoms are doubly bridged by µ1,5-dca ligands, whereas in 2 the nickel atoms are bridged by a single µ1,5-dca ligand. The magnetic measurements indicate that whereas intrachain interactions take place between the metal ions for compound 1 (J = -0.26 cm-1), no evidence for any exchange coupling is found for compound 2. © 2005 Elsevier B.V. All rights reserved.

AB - Two new dicyanamide bridged complexes [Mn(µ1,5-dca) 2(salicyh)2]n (1) and {[Ni(µ1,5- dca)(TTA)](ClO4)}n (2) (dca = dicyanamide, N(CN) 2-; salicyh = salicylic hydrazide; TTA = triethylenetetramine) have been synthesised and structurally characterised. Both the compounds 1 and 2 consist in 1-D coordination polymers. In 1 the manganese atoms are doubly bridged by µ1,5-dca ligands, whereas in 2 the nickel atoms are bridged by a single µ1,5-dca ligand. The magnetic measurements indicate that whereas intrachain interactions take place between the metal ions for compound 1 (J = -0.26 cm-1), no evidence for any exchange coupling is found for compound 2. © 2005 Elsevier B.V. All rights reserved.

KW - Dicyanamide

KW - Magnetic studies

KW - Manganese(II), Nickel(II) complexes

KW - Structural studies

UR - https://www.scopus.com/pages/publications/28544445907

U2 - 10.1016/j.ica.2005.08.006

DO - 10.1016/j.ica.2005.08.006

M3 - Article

SN - 1873-3255

VL - 358

SP - 4534

EP - 4540

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 15

ER -

Sen S, Talukder P, Mitra S, Rosair G, Yap G, Gramlich V et al. Two new 1-D dicyanamide bridged polymeric complexes [Mn(μ_1,5- dca)₂(salicyh)₂]_n and {[Ni(μ_1,5- dca)(TTA)](ClO₄)}_n (dca = dicyanamide, N(CN) ₂^-; salicyh = salicylic hydrazide; TTA = triethylenetetramine): Synthesis, structures and magnetic studies. Inorganica Chimica Acta. 2005 Dec 1;358(15):4534-4540. doi: 10.1016/j.ica.2005.08.006