Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing TiIII/TiIV

Ann M. Chippindale; Mark R. Grimshaw; Anthony V. Powell; Andrew R. Cowley

doi:10.1021/ic050399y

Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti^III/Ti^IV

Ann M. Chippindale, Mark R. Grimshaw, Anthony V. Powell, Andrew R. Cowley

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The first 3-D open-framework TiGaPO complex, constructed from Ti ^IIIO₆, Ti^IVO₆, GaO₄, and PO₄ polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. © 2005 American Chemical Society.

Original language	English
Pages (from-to)	4121-4123
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	12
DOIs	https://doi.org/10.1021/ic050399y
Publication status	Published - 13 Jun 2005

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title = "Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing TiIII/TiIV",

abstract = "The first 3-D open-framework TiGaPO complex, constructed from Ti IIIO6, TiIVO6, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. {\textcopyright} 2005 American Chemical Society.",

author = "Chippindale, {Ann M.} and Grimshaw, {Mark R.} and Powell, {Anthony V.} and Cowley, {Andrew R.}",

year = "2005",

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doi = "10.1021/ic050399y",

language = "English",

volume = "44",

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journal = "Inorganic Chemistry",

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AU - Chippindale, Ann M.

AU - Grimshaw, Mark R.

AU - Powell, Anthony V.

AU - Cowley, Andrew R.

PY - 2005/6/13

Y1 - 2005/6/13

N2 - The first 3-D open-framework TiGaPO complex, constructed from Ti IIIO6, TiIVO6, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. © 2005 American Chemical Society.

AB - The first 3-D open-framework TiGaPO complex, constructed from Ti IIIO6, TiIVO6, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. © 2005 American Chemical Society.

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U2 - 10.1021/ic050399y

DO - 10.1021/ic050399y

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SN - 1520-510X

VL - 44

SP - 4121

EP - 4123

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti^III/Ti^IV

Abstract

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