Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing TiIII/TiIV

Ann M. Chippindale, Mark R. Grimshaw, Anthony V. Powell, Andrew R. Cowley

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The first 3-D open-framework TiGaPO complex, constructed from Ti IIIO6, TiIVO6, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. © 2005 American Chemical Society.

Original languageEnglish
Pages (from-to)4121-4123
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number12
DOIs
Publication statusPublished - 13 Jun 2005

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