Thermodynamics of liquid (xenon + methane) mixtures

Lino M. B. Dias, Eduardo J. M. Filipe, Clare McCabe, Jorge C. G. Calado*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

A new apparatus for the study of vapor-liquid or vapor-liquid-liquid equilibrium has been assembled. The apparatus, based on a static and analytical method, can perform measurements at temperatures from 185 to 320 K and pressures up to 8 MPa. The equilibrium vapor pressures of (xenon + methane) binary mixtures have been measured at seven temperatures, from 189.78 to 273.18 K, and at pressures up to 6.8 MPa. The mixture critical line has been estimated and found to be continuous between the critical points of the pure components. The system is found to display type I behavior in the classification scheme of Scott and van Konynenburg. The results have been correlated by the Peng-Robinson equation of state and a more rigorous theoretical study performed with the statistical associating fluid theory for potentials of variable range (SAFT-VR).

Original languageEnglish
Pages (from-to)7377-7381
Number of pages5
JournalJournal of Physical Chemistry B
Volume108
Issue number22
DOIs
Publication statusPublished - 1 Jun 2004

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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