Thermally stable luminescent zinc-Schiff base complexes: a thiocyanato bridged 1D coordination polymer and a supramolecular 1D polymer

Monami Maiti; Santarupa Thakurta; Dipali Sadhukhan; Guillaume Pilet; Georgina Margaret Rosair; Aline Nonat; Loïc J Charbonnière; Samiran Mitra

doi:10.1016/j.poly.2013.08.009

Thermally stable luminescent zinc-Schiff base complexes: a thiocyanato bridged 1D coordination polymer and a supramolecular 1D polymer

Monami Maiti, Santarupa Thakurta, Dipali Sadhukhan, Guillaume Pilet, Georgina Margaret Rosair, Aline Nonat, Loïc J Charbonnière, Samiran Mitra^*

^*Corresponding author for this work

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

A single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit [Zn2L1(mu(1,3)-SCN)(SCH)](n) (1) and a dimeric zinc complex [Zn2L2(NCS)(OOCCH3)(CH3OH)(2)] (2) have been synthesized using two different Schiff bases N,N'-bis(3-methoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-1) and N,N'-bis(3-ethoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-2), respectively. All the ligands and the complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analysis has been performed to investigate their thermal stability. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach. (C) 2013 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	6-15
Number of pages	10
Journal	Polyhedron
Volume	65
DOIs	https://doi.org/10.1016/j.poly.2013.08.009
Publication status	Published - 28 Nov 2013

Keywords

Zinc(II)-Schiff base polymer
Crystal structure
Thiocyanate bridge
Supramolecular chain
Photophysical studies
CRYSTAL-STRUCTURES
MAGNETIC-PROPERTIES
DINUCLEAR COMPLEXES
QUANTUM YIELDS
LIGAND
COPPER(II)
FLUORESCENCE
ZN(II)
CU(II)
SALICYLALDEHYDE

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title = "Thermally stable luminescent zinc-Schiff base complexes: a thiocyanato bridged 1D coordination polymer and a supramolecular 1D polymer",

abstract = "A single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit [Zn2L1(mu(1,3)-SCN)(SCH)](n) (1) and a dimeric zinc complex [Zn2L2(NCS)(OOCCH3)(CH3OH)(2)] (2) have been synthesized using two different Schiff bases N,N'-bis(3-methoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-1) and N,N'-bis(3-ethoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-2), respectively. All the ligands and the complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analysis has been performed to investigate their thermal stability. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach. (C) 2013 Elsevier Ltd. All rights reserved.",

keywords = "Zinc(II)-Schiff base polymer, Crystal structure, Thiocyanate bridge, Supramolecular chain, Photophysical studies, CRYSTAL-STRUCTURES, MAGNETIC-PROPERTIES, DINUCLEAR COMPLEXES, QUANTUM YIELDS, LIGAND, COPPER(II), FLUORESCENCE, ZN(II), CU(II), SALICYLALDEHYDE",

author = "Monami Maiti and Santarupa Thakurta and Dipali Sadhukhan and Guillaume Pilet and Rosair, {Georgina Margaret} and Aline Nonat and Charbonni{\`e}re, {Lo{\"i}c J} and Samiran Mitra",

year = "2013",

month = nov,

day = "28",

doi = "10.1016/j.poly.2013.08.009",

language = "English",

volume = "65",

pages = "6--15",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

TY - JOUR

T1 - Thermally stable luminescent zinc-Schiff base complexes

T2 - a thiocyanato bridged 1D coordination polymer and a supramolecular 1D polymer

AU - Maiti, Monami

AU - Thakurta, Santarupa

AU - Sadhukhan, Dipali

AU - Pilet, Guillaume

AU - Rosair, Georgina Margaret

AU - Nonat, Aline

AU - Charbonnière, Loïc J

AU - Mitra, Samiran

PY - 2013/11/28

Y1 - 2013/11/28

N2 - A single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit [Zn2L1(mu(1,3)-SCN)(SCH)](n) (1) and a dimeric zinc complex [Zn2L2(NCS)(OOCCH3)(CH3OH)(2)] (2) have been synthesized using two different Schiff bases N,N'-bis(3-methoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-1) and N,N'-bis(3-ethoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-2), respectively. All the ligands and the complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analysis has been performed to investigate their thermal stability. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach. (C) 2013 Elsevier Ltd. All rights reserved.

AB - A single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit [Zn2L1(mu(1,3)-SCN)(SCH)](n) (1) and a dimeric zinc complex [Zn2L2(NCS)(OOCCH3)(CH3OH)(2)] (2) have been synthesized using two different Schiff bases N,N'-bis(3-methoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-1) and N,N'-bis(3-ethoxysalicylidenimino)-1,3-diaminopropane ((LH2)-H-2), respectively. All the ligands and the complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analysis has been performed to investigate their thermal stability. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach. (C) 2013 Elsevier Ltd. All rights reserved.

KW - Zinc(II)-Schiff base polymer

KW - Crystal structure

KW - Thiocyanate bridge

KW - Supramolecular chain

KW - Photophysical studies

KW - CRYSTAL-STRUCTURES

KW - MAGNETIC-PROPERTIES

KW - DINUCLEAR COMPLEXES

KW - QUANTUM YIELDS

KW - LIGAND

KW - COPPER(II)

KW - FLUORESCENCE

KW - ZN(II)

KW - CU(II)

KW - SALICYLALDEHYDE

U2 - 10.1016/j.poly.2013.08.009

DO - 10.1016/j.poly.2013.08.009

M3 - Article

SN - 0277-5387

VL - 65

SP - 6

EP - 15

JO - Polyhedron

JF - Polyhedron

ER -

Thermally stable luminescent zinc-Schiff base complexes: a thiocyanato bridged 1D coordination polymer and a supramolecular 1D polymer

Abstract

Keywords

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