The electronic origin of the Ã A? ? X~ A' transition of trifluoronitrosomethane (CF3NO) has been reassigned to the very weak feature near 717.9 nm in the fluorescence excitation spectrum of the jet-cooled molecule. The prominent torsional progression has been reinpreted and the height of the threefold torsional barier in the Ã( n,p* ) state has been revised to 601.5 ± 10 cm-1. © 1987.
|Number of pages||5|
|Journal||Chemical Physics Letters|
|Publication status||Published - 17 Apr 1987|