The synthesis and structural characterisation of two polynuclear hafnium(IV) complexes

Scott J Dalgarno, Jerry L Atwood, Colin L Raston

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Attempts to form extended supramolecular structures incorporating hafnium(IV) complexes of p-sulfonatocalix[6]arene resulted in the serendipitous formation of two polynuclear-hafnium clusters. Subsequent reaction between hafnium triflate and 1 M sulfuric or p-toluenesulfonic acid solutions also led to the formation of the same clusters, identified as cations based on Hf-17 and Hf-4, respectively. (c) 2006 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)1344-1348
Number of pages5
JournalInorganica Chimica Acta
Volume360
Issue number4
DOIs
Publication statusPublished - 1 Mar 2007

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