The synthesis and structural characterisation of two polynuclear hafnium(IV) complexes

Scott J Dalgarno; Jerry L Atwood; Colin L Raston

doi:10.1016/j.ica.2006.03.018

The synthesis and structural characterisation of two polynuclear hafnium(IV) complexes

Scott J Dalgarno, Jerry L Atwood, Colin L Raston

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Abstract

Attempts to form extended supramolecular structures incorporating hafnium(IV) complexes of p-sulfonatocalix[6]arene resulted in the serendipitous formation of two polynuclear-hafnium clusters. Subsequent reaction between hafnium triflate and 1 M sulfuric or p-toluenesulfonic acid solutions also led to the formation of the same clusters, identified as cations based on Hf-17 and Hf-4, respectively. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1344-1348
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	360
Issue number	4
DOIs	https://doi.org/10.1016/j.ica.2006.03.018
Publication status	Published - 1 Mar 2007

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10.1016/j.ica.2006.03.018

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abstract = "Attempts to form extended supramolecular structures incorporating hafnium(IV) complexes of p-sulfonatocalix[6]arene resulted in the serendipitous formation of two polynuclear-hafnium clusters. Subsequent reaction between hafnium triflate and 1 M sulfuric or p-toluenesulfonic acid solutions also led to the formation of the same clusters, identified as cations based on Hf-17 and Hf-4, respectively. (c) 2006 Elsevier B.V. All rights reserved.",

author = "Dalgarno, {Scott J} and Atwood, {Jerry L} and Raston, {Colin L}",

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AU - Dalgarno, Scott J

AU - Atwood, Jerry L

AU - Raston, Colin L

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Y1 - 2007/3/1

N2 - Attempts to form extended supramolecular structures incorporating hafnium(IV) complexes of p-sulfonatocalix[6]arene resulted in the serendipitous formation of two polynuclear-hafnium clusters. Subsequent reaction between hafnium triflate and 1 M sulfuric or p-toluenesulfonic acid solutions also led to the formation of the same clusters, identified as cations based on Hf-17 and Hf-4, respectively. (c) 2006 Elsevier B.V. All rights reserved.

AB - Attempts to form extended supramolecular structures incorporating hafnium(IV) complexes of p-sulfonatocalix[6]arene resulted in the serendipitous formation of two polynuclear-hafnium clusters. Subsequent reaction between hafnium triflate and 1 M sulfuric or p-toluenesulfonic acid solutions also led to the formation of the same clusters, identified as cations based on Hf-17 and Hf-4, respectively. (c) 2006 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.ica.2006.03.018

DO - 10.1016/j.ica.2006.03.018

M3 - Article

SN - 0020-1693

VL - 360

SP - 1344

EP - 1348

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 4

ER -

The synthesis and structural characterisation of two polynuclear hafnium(IV) complexes

Abstract

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