The synthesis and molecular structure of 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→PtIV→PtII

Geoffrey K. Barker; Michael Green; F. Gordon A. Stone; Alan J. Welch; Wayne C. Wolsey

doi:10.1039/C39800000627

The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II

Geoffrey K. Barker^*, Michael Green, F. Gordon A. Stone, Alan J. Welch, Wayne C. Wolsey

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Reaction of [Pt ₂ (μ,-cyclo-octa-1,5-diene)(PEt₃)₄] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀, which on pyrolysis (100 °C) loses H₂ and forms 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; the structures of these compounds have been determined by X-ray crystallography.

Original language	English
Pages (from-to)	627-629
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39800000627
Publication status	Published - 1980

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Green, M., Stone, F. G. A., Welch, A. J., & Wolsey, W. C. (1980). The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II. Journal of the Chemical Society, Chemical Communications, (13), 627-629. https://doi.org/10.1039/C39800000627

Barker, Geoffrey K. ; Green, Michael ; Stone, F. Gordon A. et al. / The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II. In: Journal of the Chemical Society, Chemical Communications. 1980 ; No. 13. pp. 627-629.

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title = "The synthesis and molecular structure of 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→PtIV→PtII",

abstract = " Reaction of [Pt 2 (μ,-cyclo-octa-1,5-diene)(PEt3)4] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10, which on pyrolysis (100 °C) loses H2 and forms 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; the structures of these compounds have been determined by X-ray crystallography. ",

author = "Barker, {Geoffrey K.} and Michael Green and Stone, {F. Gordon A.} and Welch, {Alan J.} and Wolsey, {Wayne C.}",

year = "1980",

doi = "10.1039/C39800000627",

language = "English",

pages = "627--629",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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Barker, GK, Green, M, Stone, FGA, Welch, AJ & Wolsey, WC 1980, 'The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II', Journal of the Chemical Society, Chemical Communications, no. 13, pp. 627-629. https://doi.org/10.1039/C39800000627

The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II. / Barker, Geoffrey K.; Green, Michael; Stone, F. Gordon A. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 13, 1980, p. 627-629.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The synthesis and molecular structure of 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→PtIV→PtII

AU - Barker, Geoffrey K.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Welch, Alan J.

AU - Wolsey, Wayne C.

PY - 1980

Y1 - 1980

N2 - Reaction of [Pt 2 (μ,-cyclo-octa-1,5-diene)(PEt3)4] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10, which on pyrolysis (100 °C) loses H2 and forms 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; the structures of these compounds have been determined by X-ray crystallography.

AB - Reaction of [Pt 2 (μ,-cyclo-octa-1,5-diene)(PEt3)4] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et3P)2-μ10,11-H-7,8,9-C2PtB8H10, which on pyrolysis (100 °C) loses H2 and forms 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; the structures of these compounds have been determined by X-ray crystallography.

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U2 - 10.1039/C39800000627

DO - 10.1039/C39800000627

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SN - 0022-4936

SP - 627

EP - 629

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 13

ER -

Barker GK, Green M, Stone FGA, Welch AJ, Wolsey WC. The synthesis and molecular structure of 9-H-9,9-(Et₃P)₂-μ_10,11-H-7,8,9-C₂PtB₈H₁₀ and 9-H-9,10-(Et₃P)₂-7,8,9-C₂PtB₈H₉ ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt⁰→Pt^IV→Pt^II. Journal of the Chemical Society, Chemical Communications. 1980;(13):627-629. doi: 10.1039/C39800000627