The synthesis and molecular structure of 9-H-9,9-(Et3P)210,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; Pt(9)→B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→PtIV→PtII

Geoffrey K. Barker*, Michael Green, F. Gordon A. Stone, Alan J. Welch, Wayne C. Wolsey

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

Reaction of [Pt 2 (μ,-cyclo-octa-1,5-diene)(PEt3)4] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et3P)210,11-H-7,8,9-C2PtB8H10, which on pyrolysis (100 °C) loses H2 and forms 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9 ; the structures of these compounds have been determined by X-ray crystallography.

Original languageEnglish
Pages (from-to)627-629
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number13
DOIs
Publication statusPublished - 1980

ASJC Scopus subject areas

  • Molecular Medicine

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