The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes

R. J E Lees; Anthony V. Powell; Ann M. Chippindale

doi:10.1016/j.jpcs.2006.12.010

The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes

R. J E Lees, Anthony V. Powell, Ann M. Chippindale

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Four new antimony sulphides, [T(dien)₂]Sb₆S₁₀·xH₂O [T=Ni (1), Co (2) x˜0.45], [Co(en)₃]Sb₈S₁₃ (3) and [Ni(en)₃]Sb₁₂S₁₉ (4), have been synthesised under solvothermal conditions. In compounds (1) - (3), Sb₁₂S₂₂^8- secondary building units are connected to form layered structures. In (1) and (2), Sb₆S₁₀^2- layers containing Sb₁₆S₁₆ heterorings are separated by [T(dien]₂]²⁺ cations, whilst in (3), Sb₈S₁₃^2- layers contain [Co(en)₃]²⁺ cations within large Sb₂₂S₂₂ pores. Compound (4) adopts a three-dimensional structure in which [Ni(en)₃]²⁺ cations lie within ca. 5 Å wide channels. © 2007 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1215-1219
Number of pages	5
Journal	Journal of Physics and Chemistry of Solids
Volume	68
Issue number	5-6
DOIs	https://doi.org/10.1016/j.jpcs.2006.12.010
Publication status	Published - May 2007

Keywords

A. Chalcogenides
B. Crystal growth
C. X-ray diffraction

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10.1016/j.jpcs.2006.12.010

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@article{e7aba5637a1e43cb9b23333ee484f7ba,

title = "The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes",

abstract = "Four new antimony sulphides, [T(dien)2]Sb6S10·xH2O [T=Ni (1), Co (2) x˜0.45], [Co(en)3]Sb8S13 (3) and [Ni(en)3]Sb12S19 (4), have been synthesised under solvothermal conditions. In compounds (1) - (3), Sb12S228- secondary building units are connected to form layered structures. In (1) and (2), Sb6S102- layers containing Sb16S16 heterorings are separated by [T(dien]2]2+ cations, whilst in (3), Sb8S132- layers contain [Co(en)3]2+ cations within large Sb22S22 pores. Compound (4) adopts a three-dimensional structure in which [Ni(en)3]2+ cations lie within ca. 5 {\AA} wide channels. {\textcopyright} 2007 Elsevier Ltd. All rights reserved.",

keywords = "A. Chalcogenides, B. Crystal growth, C. X-ray diffraction",

author = "Lees, {R. J E} and Powell, {Anthony V.} and Chippindale, {Ann M.}",

year = "2007",

month = may,

doi = "10.1016/j.jpcs.2006.12.010",

language = "English",

volume = "68",

pages = "1215--1219",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier",

number = "5-6",

}

TY - JOUR

T1 - The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes

AU - Lees, R. J E

AU - Powell, Anthony V.

AU - Chippindale, Ann M.

PY - 2007/5

Y1 - 2007/5

N2 - Four new antimony sulphides, [T(dien)2]Sb6S10·xH2O [T=Ni (1), Co (2) x˜0.45], [Co(en)3]Sb8S13 (3) and [Ni(en)3]Sb12S19 (4), have been synthesised under solvothermal conditions. In compounds (1) - (3), Sb12S228- secondary building units are connected to form layered structures. In (1) and (2), Sb6S102- layers containing Sb16S16 heterorings are separated by [T(dien]2]2+ cations, whilst in (3), Sb8S132- layers contain [Co(en)3]2+ cations within large Sb22S22 pores. Compound (4) adopts a three-dimensional structure in which [Ni(en)3]2+ cations lie within ca. 5 Å wide channels. © 2007 Elsevier Ltd. All rights reserved.

AB - Four new antimony sulphides, [T(dien)2]Sb6S10·xH2O [T=Ni (1), Co (2) x˜0.45], [Co(en)3]Sb8S13 (3) and [Ni(en)3]Sb12S19 (4), have been synthesised under solvothermal conditions. In compounds (1) - (3), Sb12S228- secondary building units are connected to form layered structures. In (1) and (2), Sb6S102- layers containing Sb16S16 heterorings are separated by [T(dien]2]2+ cations, whilst in (3), Sb8S132- layers contain [Co(en)3]2+ cations within large Sb22S22 pores. Compound (4) adopts a three-dimensional structure in which [Ni(en)3]2+ cations lie within ca. 5 Å wide channels. © 2007 Elsevier Ltd. All rights reserved.

KW - A. Chalcogenides

KW - B. Crystal growth

KW - C. X-ray diffraction

U2 - 10.1016/j.jpcs.2006.12.010

DO - 10.1016/j.jpcs.2006.12.010

M3 - Article

SN - 0022-3697

VL - 68

SP - 1215

EP - 1219

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 5-6

ER -

The synthesis and characterisation of four new antimony sulphides incorporating transition-metal complexes

Abstract

Keywords

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