The mechanistic role of η2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{η5-C(CF3)=...

Laurence Carlton; Jack L. Davidson; Paul Ewing; Ljubica Manojlović-Muir; Kenneth W. Muir

The mechanistic role of η²-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{η⁵-C(CF₃)=...

Laurence Carlton, Jack L. Davidson, Paul Ewing, Ljubica Manojlović-Muir, Kenneth W. Muir

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

full title: The mechanistic role of ?²-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{?⁵-C(CF₃)= C(CF₃)C(CO ₂Me)=C(CO₂Me)C(CF₃)=C(CF₃)SPrⁱ}(?⁵-C₅H₅)], [WF{?⁵-C(=CF₂)C(CF₃)= C(CO₂Me)C(CO₂Me)C(CF₃)C(CF₃) SPrⁱ}(?⁵-C₅H₅)], and [W{?⁴-C(CF₃)C(CF₃)= C(Me)C(Me)SPr ⁱ}(?²-CF₃C=CCF₃)(?-C ₅H₅)] Reactions of alkynes RC=CR (R = CF₃, CO₂Me, or Me) with ?²-vinyl complexes [W{?²-C(CF₃)C(CF₃)SR'}(CF ₃C=CCF ₃)-(?⁵-C₅H₅)] (R' = Et, Prⁿ, or Prⁱ) give isomeric products [W(CF₃C₂CF₃)₂(RC₂ R)SR'(?⁵-C₅H₅)] resulting from insertion of the incoming alkyne into the M=C bond of the ?²- vinyl and thus illustrate that ?²-vinyls can act as intermediates in metal-promoted alkyne oligomerisation reactions.

Original language	English
Pages (from-to)	1474-1476
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
Publication status	Published - 1985

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@article{a105d746b6674b8d91e77cd079a94136,

title = "The mechanistic role of η2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{η5-C(CF3)=...",

abstract = "full title: The mechanistic role of ?2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{?5-C(CF3)= C(CF3)C(CO 2Me)=C(CO2Me)C(CF3)=C(CF3)SPri }(?5-C5H5)], [WF{?5-C(=CF2)C(CF3)= C(CO2Me)C(CO2Me)C(CF3)C(CF3) SPri}(?5-C5H5)], and [W{?4-C(CF3)C(CF3)= C(Me)C(Me)SPr i}(?2-CF3C=CCF3)(?-C 5H5)] Reactions of alkynes RC=CR (R = CF3, CO2Me, or Me) with ?2-vinyl complexes [W{?2-C(CF3)C(CF3)SR'}(CF 3C=CCF 3)-(?5-C5H5)] (R' = Et, Prn, or Pri) give isomeric products [W(CF3C2CF3)2(RC2 R)SR'(?5-C5H5)] resulting from insertion of the incoming alkyne into the M=C bond of the ?2- vinyl and thus illustrate that ?2-vinyls can act as intermediates in metal-promoted alkyne oligomerisation reactions.",

author = "Laurence Carlton and Davidson, {Jack L.} and Paul Ewing and Ljubica Manojlovi{\'c}-Muir and Muir, {Kenneth W.}",

year = "1985",

language = "English",

pages = "1474--1476",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "21",

}

TY - JOUR

T1 - The mechanistic role of η2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{η5-C(CF3)=...

AU - Carlton, Laurence

AU - Davidson, Jack L.

AU - Ewing, Paul

AU - Manojlović-Muir, Ljubica

AU - Muir, Kenneth W.

PY - 1985

Y1 - 1985

N2 - full title: The mechanistic role of ?2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{?5-C(CF3)= C(CF3)C(CO 2Me)=C(CO2Me)C(CF3)=C(CF3)SPri }(?5-C5H5)], [WF{?5-C(=CF2)C(CF3)= C(CO2Me)C(CO2Me)C(CF3)C(CF3) SPri}(?5-C5H5)], and [W{?4-C(CF3)C(CF3)= C(Me)C(Me)SPr i}(?2-CF3C=CCF3)(?-C 5H5)] Reactions of alkynes RC=CR (R = CF3, CO2Me, or Me) with ?2-vinyl complexes [W{?2-C(CF3)C(CF3)SR'}(CF 3C=CCF 3)-(?5-C5H5)] (R' = Et, Prn, or Pri) give isomeric products [W(CF3C2CF3)2(RC2 R)SR'(?5-C5H5)] resulting from insertion of the incoming alkyne into the M=C bond of the ?2- vinyl and thus illustrate that ?2-vinyls can act as intermediates in metal-promoted alkyne oligomerisation reactions.

AB - full title: The mechanistic role of ?2-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{?5-C(CF3)= C(CF3)C(CO 2Me)=C(CO2Me)C(CF3)=C(CF3)SPri }(?5-C5H5)], [WF{?5-C(=CF2)C(CF3)= C(CO2Me)C(CO2Me)C(CF3)C(CF3) SPri}(?5-C5H5)], and [W{?4-C(CF3)C(CF3)= C(Me)C(Me)SPr i}(?2-CF3C=CCF3)(?-C 5H5)] Reactions of alkynes RC=CR (R = CF3, CO2Me, or Me) with ?2-vinyl complexes [W{?2-C(CF3)C(CF3)SR'}(CF 3C=CCF 3)-(?5-C5H5)] (R' = Et, Prn, or Pri) give isomeric products [W(CF3C2CF3)2(RC2 R)SR'(?5-C5H5)] resulting from insertion of the incoming alkyne into the M=C bond of the ?2- vinyl and thus illustrate that ?2-vinyls can act as intermediates in metal-promoted alkyne oligomerisation reactions.

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M3 - Article

SN - 0022-4936

SP - 1474

EP - 1476

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 21

ER -

The mechanistic role of η²-vinyl complexes in metal-promoted alkyne Oligomerisations. The crystal and molecular structures of [W{η⁵-C(CF₃)=...

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