The gas phase i.r. spectra of some perhalonitrosomethanes

N. P. Ernsting; J. Pfab

The gas phase i.r. spectra of some perhalonitrosomethanes

N. P. Ernsting, J. Pfab

School of Engineering & Physical Sciences

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16 Citations (Scopus)

Abstract

The gas phase i.r. spectra of the nitrosomethanes CClF₂NO, CCl₂FNO, CCl₃NO, CBrCl₂NO, CBr₂ClNO and CBr₃NO in the 3300-200 cm^-1 region have been examined. It is concluded that CBr₂ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl₃NO and its heavier derivatives, the spectral region between 1000 and 500 cm^-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

Original language	English
Pages (from-to)	75-84
Number of pages	10
Journal	Spectrochimica Acta Part A: Molecular Spectroscopy
Volume	36
Issue number	1
Publication status	Published - 1980

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title = "The gas phase i.r. spectra of some perhalonitrosomethanes",

abstract = "The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. {\textcopyright} 1980.",

author = "Ernsting, {N. P.} and J. Pfab",

year = "1980",

language = "English",

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journal = "Spectrochimica Acta Part A: Molecular Spectroscopy",

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T1 - The gas phase i.r. spectra of some perhalonitrosomethanes

AU - Ernsting, N. P.

AU - Pfab, J.

PY - 1980

Y1 - 1980

N2 - The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

AB - The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

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M3 - Article

SN - 0584-8539

VL - 36

SP - 75

EP - 84

JO - Spectrochimica Acta Part A: Molecular Spectroscopy

JF - Spectrochimica Acta Part A: Molecular Spectroscopy

IS - 1

ER -

The gas phase i.r. spectra of some perhalonitrosomethanes

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