The gas phase i.r. spectra of some perhalonitrosomethanes

N. P. Ernsting, J. Pfab

Research output: Contribution to journalArticle

Abstract

The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

Original languageEnglish
Pages (from-to)75-84
Number of pages10
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume36
Issue number1
Publication statusPublished - 1980

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title = "The gas phase i.r. spectra of some perhalonitrosomethanes",
abstract = "The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. {\circledC} 1980.",
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The gas phase i.r. spectra of some perhalonitrosomethanes. / Ernsting, N. P.; Pfab, J.

In: Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 36, No. 1, 1980, p. 75-84.

Research output: Contribution to journalArticle

TY - JOUR

T1 - The gas phase i.r. spectra of some perhalonitrosomethanes

AU - Ernsting, N. P.

AU - Pfab, J.

PY - 1980

Y1 - 1980

N2 - The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

AB - The gas phase i.r. spectra of the nitrosomethanes CClF2NO, CCl2FNO, CCl3NO, CBrCl2NO, CBr2ClNO and CBr3NO in the 3300-200 cm-1 region have been examined. It is concluded that CBr2ClNO exists in two stable isomeric forms with a cis and gauche conformation respectively. For CCl3NO and its heavier derivatives, the spectral region between 1000 and 500 cm-1 is likely to contain more fundamental vibrations than can be inferred from the related aldehydes. The spectra are compared and assignments are suggested for the observed bands. © 1980.

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M3 - Article

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JO - Spectrochimica Acta Part A: Molecular Spectroscopy

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