The first supraicosahedrai p-block metallacarboranes

N. M M Wilson, David Ellis, A. S F Boyd, Barry T. Giles, Stuart A. Macgregor, Georgina M. Rosair, Alan J. Welch

Research output: Contribution to journalArticle

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Abstract

Reaction of Na2[7,9-C2B10H12] or its C-dimethyl analogue with SnCl2 in THF affords 4,1,6-closo-SnC2B10H12 or 1,6-Me2-4,1,6-closo-SnC2B10H10 respectively, the first 13-vertex metallacarboranes involving p-block metals; spectroscopic, structural and theoretical studies, including an analysis of fluctionality in solution, are reported.

Original languageEnglish
Pages (from-to)464-465
Number of pages2
JournalChemical Communications
Issue number5
Publication statusPublished - 7 Mar 2002

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    Wilson, N. M. M., Ellis, D., Boyd, A. S. F., Giles, B. T., Macgregor, S. A., Rosair, G. M., & Welch, A. J. (2002). The first supraicosahedrai p-block metallacarboranes. Chemical Communications, (5), 464-465.