The first 4,1,10-MC2B10 supraicosahedral metallacarboranes and a route to previously inaccessible 4,1,12-ruthenium arene species

David Ellis; M E Lopez; Ruaraidh McIntosh; Georgina M. Rosair; Alan J. Welch; Romain Quenardelle

doi:10.1039/b416646a

The first 4,1,10-MC₂B₁₀ supraicosahedral metallacarboranes and a route to previously inaccessible 4,1,12-ruthenium arene species

David Ellis, M E Lopez, Ruaraidh McIntosh, Georgina M. Rosair, Alan J. Welch, Romain Quenardelle

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Reduction of 1,12-closo-C₂B₁₀H₁₂ or its C,C-dimethyl analogue with sodium in liquid ammonia followed by metallation with {CpCo}²⁺, {(arene)Ru}²⁺ or {(dppe)Ni}²⁺ fragments affords the first examples of 4,1,10-MC₂B₁₀ species; thermolysis of these yields the appropriate 4,1,12-MC₂B ₁₀ isomers, unavailable for (arene)Ru metallacarboranes by similar thermolysis of known 4,1,6-MC₂B₁₀ compounds. © The Royal Society of Chemistry 2005.

Original language	English
Pages (from-to)	1348-1350
Number of pages	3
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b416646a
Publication status	Published - 14 Mar 2005

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abstract = "Reduction of 1,12-closo-C2B10H12 or its C,C-dimethyl analogue with sodium in liquid ammonia followed by metallation with {CpCo}2+, {(arene)Ru}2+ or {(dppe)Ni}2+ fragments affords the first examples of 4,1,10-MC2B10 species; thermolysis of these yields the appropriate 4,1,12-MC2B 10 isomers, unavailable for (arene)Ru metallacarboranes by similar thermolysis of known 4,1,6-MC2B10 compounds. {\textcopyright} The Royal Society of Chemistry 2005.",

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AU - McIntosh, Ruaraidh

AU - Rosair, Georgina M.

AU - Welch, Alan J.

AU - Quenardelle, Romain

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AB - Reduction of 1,12-closo-C2B10H12 or its C,C-dimethyl analogue with sodium in liquid ammonia followed by metallation with {CpCo}2+, {(arene)Ru}2+ or {(dppe)Ni}2+ fragments affords the first examples of 4,1,10-MC2B10 species; thermolysis of these yields the appropriate 4,1,12-MC2B 10 isomers, unavailable for (arene)Ru metallacarboranes by similar thermolysis of known 4,1,6-MC2B10 compounds. © The Royal Society of Chemistry 2005.

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The first 4,1,10-MC₂B₁₀ supraicosahedral metallacarboranes and a route to previously inaccessible 4,1,12-ruthenium arene species

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