The electrochemical polymerisation of a [2]rotaxane

Graeme Cooke, James F. Garety, Suhil Mabruk, Gouher Rabani, Vincent M. Rotello, Gheorghe Surpateanu, Patrice Woisel

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

We report the synthesis of a dithienylpyrrole-stoppered rotaxane and its subsequent electrochemical polymerisation onto a platinum working electrode surface. We have shown that the tetracationic cyclophane moiety of the rotaxane does not impair electropolymerisation of this derivative. Indeed, functionalised films can be conveniently prepared by oxidative polymerisation of the dithienylpyrrole stopper units, to yield a network of rotaxane units interconnected by a conducting polymer backbone. © 2005 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)783-786
Number of pages4
JournalTetrahedron Letters
Volume47
Issue number5
DOIs
Publication statusPublished - 30 Jan 2006

Keywords

  • Electrochemistry
  • Electropolymerisation
  • Rotaxane
  • Supramolecular chemistry

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