The effect of uniaxial deformation on swollen gels

S L Shenoy

doi:10.1016/S0966-7822(98)00036-7

The effect of uniaxial deformation on swollen gels

S L Shenoy

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The effect of uniaxial deformation on swollen gels is investigated. The elastic contribution is obtained by a extension of the modified Flory model proposed previously. Following Bastide, it is assumed that the deformation occurs by a process of topological rearrangements of the cross-link junctions. Consequently, the contracted junction affine model is used to describe the relationship between the macroscopic deformation and the resulting chain deformation. Using this simple approach, we examine the effect of deformation on the relative degree of swelling (F_g/F_gm) and the packing factor. © 1999 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	455-470
Number of pages	16
Journal	Polymer Gels and Networks
Volume	6
Issue number	6
DOIs	https://doi.org/10.1016/S0966-7822(98)00036-7
Publication status	Published - Dec 1998

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title = "The effect of uniaxial deformation on swollen gels",

abstract = "The effect of uniaxial deformation on swollen gels is investigated. The elastic contribution is obtained by a extension of the modified Flory model proposed previously. Following Bastide, it is assumed that the deformation occurs by a process of topological rearrangements of the cross-link junctions. Consequently, the contracted junction affine model is used to describe the relationship between the macroscopic deformation and the resulting chain deformation. Using this simple approach, we examine the effect of deformation on the relative degree of swelling (Fg/Fgm) and the packing factor. {\textcopyright} 1999 Elsevier Science Ltd. All rights reserved.",

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AB - The effect of uniaxial deformation on swollen gels is investigated. The elastic contribution is obtained by a extension of the modified Flory model proposed previously. Following Bastide, it is assumed that the deformation occurs by a process of topological rearrangements of the cross-link junctions. Consequently, the contracted junction affine model is used to describe the relationship between the macroscopic deformation and the resulting chain deformation. Using this simple approach, we examine the effect of deformation on the relative degree of swelling (Fg/Fgm) and the packing factor. © 1999 Elsevier Science Ltd. All rights reserved.

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JO - Polymer Gels and Networks

JF - Polymer Gels and Networks

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ER -

The effect of uniaxial deformation on swollen gels

Abstract

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