The effect of replacing the α-hydrogen with a methyl group on the miscibility of systems containing styrene, methacrylonitrile and methyl methacrylate

J. M G Cowie; L. M. Watson; I. J. McEwen

doi:10.1007/BF00300134

The effect of replacing the α-hydrogen with a methyl group on the miscibility of systems containing styrene, methacrylonitrile and methyl methacrylate

J. M G Cowie, L. M. Watson, I. J. McEwen

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The phase boundaries as a function of copolymer composition have been established in one polymer/copolymer and two copolymer/copolymer blend systems involving the repeat unit methacrylonitrile. Using the critical conditions for miscibility according to the Flory-Huggins theory, and an overall blend interaction parameter (B_blend) expressed in terms of repeat unit interactions B_i-j, values of B_S-MAN and B_MMA-MAN have been determined. These are compared with the corresponding acrylonitrile interactions. © 1993 Springer-Verlag.

Original language	English
Pages (from-to)	729-736
Number of pages	8
Journal	Polymer Bulletin
Volume	31
Issue number	6
DOIs	https://doi.org/10.1007/BF00300134
Publication status	Published - Dec 1993

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10.1007/BF00300134

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title = "The effect of replacing the α-hydrogen with a methyl group on the miscibility of systems containing styrene, methacrylonitrile and methyl methacrylate",

abstract = "The phase boundaries as a function of copolymer composition have been established in one polymer/copolymer and two copolymer/copolymer blend systems involving the repeat unit methacrylonitrile. Using the critical conditions for miscibility according to the Flory-Huggins theory, and an overall blend interaction parameter (Bblend) expressed in terms of repeat unit interactions Bi-j, values of BS-MAN and BMMA-MAN have been determined. These are compared with the corresponding acrylonitrile interactions. {\textcopyright} 1993 Springer-Verlag.",

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AU - Watson, L. M.

AU - McEwen, I. J.

PY - 1993/12

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N2 - The phase boundaries as a function of copolymer composition have been established in one polymer/copolymer and two copolymer/copolymer blend systems involving the repeat unit methacrylonitrile. Using the critical conditions for miscibility according to the Flory-Huggins theory, and an overall blend interaction parameter (Bblend) expressed in terms of repeat unit interactions Bi-j, values of BS-MAN and BMMA-MAN have been determined. These are compared with the corresponding acrylonitrile interactions. © 1993 Springer-Verlag.

AB - The phase boundaries as a function of copolymer composition have been established in one polymer/copolymer and two copolymer/copolymer blend systems involving the repeat unit methacrylonitrile. Using the critical conditions for miscibility according to the Flory-Huggins theory, and an overall blend interaction parameter (Bblend) expressed in terms of repeat unit interactions Bi-j, values of BS-MAN and BMMA-MAN have been determined. These are compared with the corresponding acrylonitrile interactions. © 1993 Springer-Verlag.

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DO - 10.1007/BF00300134

M3 - Article

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EP - 736

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 6

ER -

The effect of replacing the α-hydrogen with a methyl group on the miscibility of systems containing styrene, methacrylonitrile and methyl methacrylate

Abstract

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