The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Alexander J. Graham; Jin Chong Tan; David R. Allan; Stephen A. Moggach

doi:10.1039/c1cc16045a

The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Alexander J. Graham
, Jin Chong Tan
, David R. Allan
, Stephen A. Moggach^*

^*Corresponding author for this work

School of Energy, Geoscience, Infrastructure and Society

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.

Original language	English
Pages (from-to)	1535-1537
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc16045a
Publication status	Published - 1 Feb 2012

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
General Chemistry

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title = "The effect of pressure on Cu-btc: Framework compression vs. guest inclusion",

abstract = "Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.",

author = "Graham, \{Alexander J.\} and Tan, \{Jin Chong\} and Allan, \{David R.\} and Moggach, \{Stephen A.\}",

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AU - Graham, Alexander J.

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AU - Allan, David R.

AU - Moggach, Stephen A.

PY - 2012/2/1

Y1 - 2012/2/1

N2 - Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.

AB - Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.

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DO - 10.1039/c1cc16045a

M3 - Article

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AN - SCOPUS:84855650447

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JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Abstract

ASJC Scopus subject areas

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