The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Alexander J. Graham; Jin Chong Tan; David R. Allan; Stephen A. Moggach

doi:10.1039/c1cc16045a

The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Alexander J. Graham, Jin Chong Tan, David R. Allan, Stephen A. Moggach^*

^*Corresponding author for this work

School of Energy, Geoscience, Infrastructure and Society

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.

Original language	English
Pages (from-to)	1535-1537
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc16045a
Publication status	Published - 1 Feb 2012

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

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title = "The effect of pressure on Cu-btc: Framework compression vs. guest inclusion",

abstract = "Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.",

author = "Graham, {Alexander J.} and Tan, {Jin Chong} and Allan, {David R.} and Moggach, {Stephen A.}",

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AU - Allan, David R.

AU - Moggach, Stephen A.

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Y1 - 2012/2/1

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AB - Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.

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The effect of pressure on Cu-btc: Framework compression vs. guest inclusion

Abstract

ASJC Scopus subject areas

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