The effect of high pressure on MOF-5: Guest-induced modification of pore size and content at high pressure

Alexander J. Graham; David R. Allan; Anna Muszkiewicz; Carole A. Morrison; Stephen A. Moggach

doi:10.1002/anie.201104285

The effect of high pressure on MOF-5: Guest-induced modification of pore size and content at high pressure

Alexander J. Graham, David R. Allan, Anna Muszkiewicz, Carole A. Morrison, Stephen A. Moggach^*

^*Corresponding author for this work

School of Energy, Geoscience, Infrastructure and Society

Research output: Contribution to journal › Article › peer-review

116 Citations (Scopus)

Abstract

Grace under pressure: In the first high-pressure crystallographic study on the metal-organic framework MOF-5, increasing pressure initially results in the pressure-transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa.

Original language	English
Pages (from-to)	11138-11141
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	47
DOIs	https://doi.org/10.1002/anie.201104285
Publication status	Published - 18 Nov 2011

Keywords

crystal engineering
metal-organic frameworks
microporous materials

ASJC Scopus subject areas

Chemistry(all)
Catalysis

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10.1002/anie.201104285

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abstract = "Grace under pressure: In the first high-pressure crystallographic study on the metal-organic framework MOF-5, increasing pressure initially results in the pressure-transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa.",

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AU - Morrison, Carole A.

AU - Moggach, Stephen A.

PY - 2011/11/18

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N2 - Grace under pressure: In the first high-pressure crystallographic study on the metal-organic framework MOF-5, increasing pressure initially results in the pressure-transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa.

AB - Grace under pressure: In the first high-pressure crystallographic study on the metal-organic framework MOF-5, increasing pressure initially results in the pressure-transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa.

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KW - microporous materials

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The effect of high pressure on MOF-5: Guest-induced modification of pore size and content at high pressure

Abstract

Keywords

ASJC Scopus subject areas

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