The copolymerisation of 2,4-dicyanobut-1-ene with N-vinyl carbazole

A. Larrínaga; E. M. Elexpuru; L. M. León; J. M G Cowie; I. J. McEwen

The copolymerisation of 2,4-dicyanobut-1-ene with N-vinyl carbazole

A. Larrínaga
, E. M. Elexpuru
, L. M. León
, J. M G Cowie
, I. J. McEwen

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The copolymerisation of the monomers 2,4-dicyanobut-1-ene and N-vinyl carbazole has been studied. The presence of a charge transfer complex from these two monomers with a 1:1 stoichiometry has been established, and a value of 0.22 dm³ mol^-1 at 298 K for the equilibrium constant for complex formation has been obtained from NMR measurements. The copolymer composition data have been analyzed allowing for the participation of the complex in the propagation reactions; the results have been compared with the predictions of two simpler terminal models and with the penultimate model. © 1994.

Original language	English
Pages (from-to)	1347-1350
Number of pages	4
Journal	European Polymer Journal
Volume	30
Issue number	12
Publication status	Published - Dec 1994

Cite this

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title = "The copolymerisation of 2,4-dicyanobut-1-ene with N-vinyl carbazole",

abstract = "The copolymerisation of the monomers 2,4-dicyanobut-1-ene and N-vinyl carbazole has been studied. The presence of a charge transfer complex from these two monomers with a 1:1 stoichiometry has been established, and a value of 0.22 dm3 mol-1 at 298 K for the equilibrium constant for complex formation has been obtained from NMR measurements. The copolymer composition data have been analyzed allowing for the participation of the complex in the propagation reactions; the results have been compared with the predictions of two simpler terminal models and with the penultimate model. {\textcopyright} 1994.",

author = "A. Larr{\'i}naga and Elexpuru, \{E. M.\} and Le{\'o}n, \{L. M.\} and Cowie, \{J. M G\} and McEwen, \{I. J.\}",

year = "1994",

month = dec,

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journal = "European Polymer Journal",

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T1 - The copolymerisation of 2,4-dicyanobut-1-ene with N-vinyl carbazole

AU - Larrínaga, A.

AU - Elexpuru, E. M.

AU - León, L. M.

AU - Cowie, J. M G

AU - McEwen, I. J.

PY - 1994/12

Y1 - 1994/12

N2 - The copolymerisation of the monomers 2,4-dicyanobut-1-ene and N-vinyl carbazole has been studied. The presence of a charge transfer complex from these two monomers with a 1:1 stoichiometry has been established, and a value of 0.22 dm3 mol-1 at 298 K for the equilibrium constant for complex formation has been obtained from NMR measurements. The copolymer composition data have been analyzed allowing for the participation of the complex in the propagation reactions; the results have been compared with the predictions of two simpler terminal models and with the penultimate model. © 1994.

AB - The copolymerisation of the monomers 2,4-dicyanobut-1-ene and N-vinyl carbazole has been studied. The presence of a charge transfer complex from these two monomers with a 1:1 stoichiometry has been established, and a value of 0.22 dm3 mol-1 at 298 K for the equilibrium constant for complex formation has been obtained from NMR measurements. The copolymer composition data have been analyzed allowing for the participation of the complex in the propagation reactions; the results have been compared with the predictions of two simpler terminal models and with the penultimate model. © 1994.

UR - https://www.scopus.com/pages/publications/0028730138

M3 - Article

SN - 0014-3057

VL - 30

SP - 1347

EP - 1350

JO - European Polymer Journal

JF - European Polymer Journal

IS - 12

ER -

The copolymerisation of 2,4-dicyanobut-1-ene with N-vinyl carbazole

Abstract

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