The coordination complexes of nitrosobenzene with tin(IV) chloride and titanium(IV) chloride

Mailer Cameron, Brian G. Gowenlock

Research output: Contribution to journalArticle

Abstract

Coordination complexes of nitrosobenzene with tin and titanium tetrachlorides have been prepared and subjected to solid-state 13C NMR spectroscopy. The absence of resonances above 160 ppm characteristic of CNO and the presence of resonances of quaternary carbons in the range characteristic of CN2O2C suggests that the cis-dimer of nitrosobenzene is acting as a bidentate donor. © 1992.

Original languageEnglish
Pages (from-to)2781-2782
Number of pages2
JournalPolyhedron
Volume11
Issue number21
Publication statusPublished - 1992

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Tin
Coordination Complexes
Titanium
Chlorides
Dimers
Nuclear magnetic resonance spectroscopy
Carbon
nitrosobenzene
stannic chloride
titanium tetrachloride

Cite this

Cameron, Mailer ; Gowenlock, Brian G. / The coordination complexes of nitrosobenzene with tin(IV) chloride and titanium(IV) chloride. In: Polyhedron. 1992 ; Vol. 11, No. 21. pp. 2781-2782.
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Cameron, M & Gowenlock, BG 1992, 'The coordination complexes of nitrosobenzene with tin(IV) chloride and titanium(IV) chloride', Polyhedron, vol. 11, no. 21, pp. 2781-2782.

The coordination complexes of nitrosobenzene with tin(IV) chloride and titanium(IV) chloride. / Cameron, Mailer; Gowenlock, Brian G.

In: Polyhedron, Vol. 11, No. 21, 1992, p. 2781-2782.

Research output: Contribution to journalArticle

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AU - Cameron, Mailer

AU - Gowenlock, Brian G.

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AB - Coordination complexes of nitrosobenzene with tin and titanium tetrachlorides have been prepared and subjected to solid-state 13C NMR spectroscopy. The absence of resonances above 160 ppm characteristic of CNO and the presence of resonances of quaternary carbons in the range characteristic of CN2O2C suggests that the cis-dimer of nitrosobenzene is acting as a bidentate donor. © 1992.

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