The C-N bond dissociation energy in nitrosyl cyanide

Brian G. Gowenlock; C. A F Johnson; Colin M. Keary; Josef Pfab

The C-N bond dissociation energy in nitrosyl cyanide

Brian G. Gowenlock, C. A F Johnson, Colin M. Keary, Josef Pfab

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

D(NC-NO) has been determined by an electron impact method. The value obtained is 28.8 ± 2.5 kcal mol^-1 (120.5 ± 11.5 kJ mol^-1). This value is compared with those obtained for other nitroso-compounds and it is concluded that there is no simple relation between C-N bond dissociation energy and bond length in these compounds, the predominant contribution to the bond dissociation energy being the reorganisation energy in the liberated nitric oxide.

Original language	English
Pages (from-to)	351-
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	4
Publication status	Published - 1975

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title = "The C-N bond dissociation energy in nitrosyl cyanide",

abstract = "D(NC-NO) has been determined by an electron impact method. The value obtained is 28.8 ± 2.5 kcal mol-1 (120.5 ± 11.5 kJ mol-1). This value is compared with those obtained for other nitroso-compounds and it is concluded that there is no simple relation between C-N bond dissociation energy and bond length in these compounds, the predominant contribution to the bond dissociation energy being the reorganisation energy in the liberated nitric oxide.",

author = "Gowenlock, {Brian G.} and Johnson, {C. A F} and Keary, {Colin M.} and Josef Pfab",

year = "1975",

language = "English",

pages = "351--",

journal = "Journal of the Chemical Society, Perkin Transactions 2",

issn = "1472-779X",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - The C-N bond dissociation energy in nitrosyl cyanide

AU - Gowenlock, Brian G.

AU - Johnson, C. A F

AU - Keary, Colin M.

AU - Pfab, Josef

PY - 1975

Y1 - 1975

N2 - D(NC-NO) has been determined by an electron impact method. The value obtained is 28.8 ± 2.5 kcal mol-1 (120.5 ± 11.5 kJ mol-1). This value is compared with those obtained for other nitroso-compounds and it is concluded that there is no simple relation between C-N bond dissociation energy and bond length in these compounds, the predominant contribution to the bond dissociation energy being the reorganisation energy in the liberated nitric oxide.

AB - D(NC-NO) has been determined by an electron impact method. The value obtained is 28.8 ± 2.5 kcal mol-1 (120.5 ± 11.5 kJ mol-1). This value is compared with those obtained for other nitroso-compounds and it is concluded that there is no simple relation between C-N bond dissociation energy and bond length in these compounds, the predominant contribution to the bond dissociation energy being the reorganisation energy in the liberated nitric oxide.

M3 - Article

SN - 1472-779X

SP - 351-

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

IS - 4

ER -

The C-N bond dissociation energy in nitrosyl cyanide

Abstract

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