The absolute entropies of SiH2 and SiH3

P. John, J. H. Purnell

Research output: Contribution to journalArticle

Abstract

The absolute entropies and free energy functions between 200°K and 900°K for the singlet state of silene (1SiH2) have been calculated using recently established molecular parameters. Similar calculations have been performed for silyl (SiH3) using recently measured parameters and a reasonable estimate of the SiH bond length. These data allow estimation of the equilibrium constants of the reactions {A figure is presented}{A figure is presented} The implications of the above data with respect to the mechanism of monosilane pyrolysis are outlined.

Original languageEnglish
Pages (from-to)233-236
Number of pages4
JournalJournal of Organometallic Chemistry
Volume29
Issue number2
DOIs
Publication statusPublished - 1 Jun 1971

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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