Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H 3NCH2CH2NH2][Ag2SbS 3] and [H3NCH2CH2NH 2]2[Ag5Sb3S8]

Paz Vaqueiro; Ann M. Chippindale; Andrew R. Cowley; Anthony V. Powell

doi:10.1021/ic034926u

Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H ₃NCH₂CH₂NH₂][Ag₂SbS ₃] and [H₃NCH₂CH₂NH ₂]₂[Ag₅Sb₃S₈]

Paz Vaqueiro, Ann M. Chippindale, Andrew R. Cowley, Anthony V. Powell

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Two new silver-antimony sulfides, [C₂H₉N ₂][Ag₂SbS₃] (1) and [C₂H ₉N₂]₂[Ag₅Sb₃S ₈] (2), have been prepared solvothermally in the presence of ethylenediamine and characterized by single-crystal X-ray diffraction, thermogravimetry, and elemental analysis. Compound 1 crystallizes in the space group Pn (a = 6.1781(1) Å, b = 11.9491(3) Å, c = 6.9239(2) Å, ß = 111.164(1)°) and 2 in the space group Pm (a = 6.2215(2) Å, b = 15.7707(7) Å, c = 11.6478(5) Å, ß = 92.645(2)°). The structure of 1 consists of chains of fused five-membered Ag₂SbS ₂ rings linked to form layers, between which the template molecules reside. Compound 2 contains honeycomb-like sheets of fused silver-antimony-sulfide six-membered rings linked to form double layers. The idealized structure can be considered to be an ordered defect derivative of that of lithium bismuthide, Li₃Bi, and represents a new solid-state structure type.

Original language	English
Pages (from-to)	7846-7851
Number of pages	6
Journal	Inorganic Chemistry
Volume	42
Issue number	24
DOIs	https://doi.org/10.1021/ic034926u
Publication status	Published - 1 Dec 2003

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@article{58c3282bc31045b89220ce717b3c2e7f,

title = "Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H 3NCH2CH2NH2][Ag2SbS 3] and [H3NCH2CH2NH 2]2[Ag5Sb3S8]",

abstract = "Two new silver-antimony sulfides, [C2H9N 2][Ag2SbS3] (1) and [C2H 9N2]2[Ag5Sb3S 8] (2), have been prepared solvothermally in the presence of ethylenediamine and characterized by single-crystal X-ray diffraction, thermogravimetry, and elemental analysis. Compound 1 crystallizes in the space group Pn (a = 6.1781(1) {\AA}, b = 11.9491(3) {\AA}, c = 6.9239(2) {\AA}, {\ss} = 111.164(1)°) and 2 in the space group Pm (a = 6.2215(2) {\AA}, b = 15.7707(7) {\AA}, c = 11.6478(5) {\AA}, {\ss} = 92.645(2)°). The structure of 1 consists of chains of fused five-membered Ag2SbS 2 rings linked to form layers, between which the template molecules reside. Compound 2 contains honeycomb-like sheets of fused silver-antimony-sulfide six-membered rings linked to form double layers. The idealized structure can be considered to be an ordered defect derivative of that of lithium bismuthide, Li3Bi, and represents a new solid-state structure type.",

author = "Paz Vaqueiro and Chippindale, {Ann M.} and Cowley, {Andrew R.} and Powell, {Anthony V.}",

year = "2003",

month = dec,

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doi = "10.1021/ic034926u",

language = "English",

volume = "42",

pages = "7846--7851",

journal = "Inorganic Chemistry",

issn = "1520-510X",

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T1 - Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H 3NCH2CH2NH2][Ag2SbS 3] and [H3NCH2CH2NH 2]2[Ag5Sb3S8]

AU - Vaqueiro, Paz

AU - Chippindale, Ann M.

AU - Cowley, Andrew R.

AU - Powell, Anthony V.

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Two new silver-antimony sulfides, [C2H9N 2][Ag2SbS3] (1) and [C2H 9N2]2[Ag5Sb3S 8] (2), have been prepared solvothermally in the presence of ethylenediamine and characterized by single-crystal X-ray diffraction, thermogravimetry, and elemental analysis. Compound 1 crystallizes in the space group Pn (a = 6.1781(1) Å, b = 11.9491(3) Å, c = 6.9239(2) Å, ß = 111.164(1)°) and 2 in the space group Pm (a = 6.2215(2) Å, b = 15.7707(7) Å, c = 11.6478(5) Å, ß = 92.645(2)°). The structure of 1 consists of chains of fused five-membered Ag2SbS 2 rings linked to form layers, between which the template molecules reside. Compound 2 contains honeycomb-like sheets of fused silver-antimony-sulfide six-membered rings linked to form double layers. The idealized structure can be considered to be an ordered defect derivative of that of lithium bismuthide, Li3Bi, and represents a new solid-state structure type.

AB - Two new silver-antimony sulfides, [C2H9N 2][Ag2SbS3] (1) and [C2H 9N2]2[Ag5Sb3S 8] (2), have been prepared solvothermally in the presence of ethylenediamine and characterized by single-crystal X-ray diffraction, thermogravimetry, and elemental analysis. Compound 1 crystallizes in the space group Pn (a = 6.1781(1) Å, b = 11.9491(3) Å, c = 6.9239(2) Å, ß = 111.164(1)°) and 2 in the space group Pm (a = 6.2215(2) Å, b = 15.7707(7) Å, c = 11.6478(5) Å, ß = 92.645(2)°). The structure of 1 consists of chains of fused five-membered Ag2SbS 2 rings linked to form layers, between which the template molecules reside. Compound 2 contains honeycomb-like sheets of fused silver-antimony-sulfide six-membered rings linked to form double layers. The idealized structure can be considered to be an ordered defect derivative of that of lithium bismuthide, Li3Bi, and represents a new solid-state structure type.

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U2 - 10.1021/ic034926u

DO - 10.1021/ic034926u

M3 - Article

SN - 1520-510X

VL - 42

SP - 7846

EP - 7851

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Templated Synthesis of the Novel Layered Silver-Antimony Sulfides [H ₃NCH₂CH₂NH₂][Ag₂SbS ₃] and [H₃NCH₂CH₂NH ₂]₂[Ag₅Sb₃S₈]

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