Synthesis of TiO2-x/W18O49 hollow double-shell and core-shell microspheres for CO2 photoreduction under visible light

Jeannie Z. Y. Tan, Stelios Gavrielides, Meltiani Belekoukia, Warren A. Thompson, Leila Negahdar, Fang Xia, M. Mercedes Maroto-Valer, Andrew M. Beale

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)
5 Downloads (Pure)

Abstract

TiO2-x/W18O49 with core-shell or double-shelled hollow microspheres were synthesized through a facile multi-step solvothermal method. The formation of the hollow microspheres with a double-shell was a result of the Kirkendall effect during the solvothermal treatment with concentrated NaOH. The advanced architecture significantly enhanced the electronic properties of TiO2-x/W18O49, improving by more than 30 times the CO2 photoreduction efficiency compared to the pristine W18O49. Operando DRIFTS measurements revealed that the yellow TiO2-x was a preferable CO2 adsorption and conversion site.

Original languageEnglish
Pages (from-to)12150-12153
Number of pages4
JournalChemical Communications
Volume56
Issue number81
Early online date27 Aug 2020
DOIs
Publication statusPublished - 18 Oct 2020

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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