Synthesis of quinazolines over recyclable Fe3O4@SiO2-PrNH2-Fe3+ nanoparticles: A green, efficient, and solvent-free protocol

Esmaiel Eidi; Mohamad Z. Kassaee; Zahra Nasresfahani; Peter T. Cummings

doi:10.1002/aoc.4573

Synthesis of quinazolines over recyclable Fe₃O₄@SiO₂-PrNH₂-Fe³⁺ nanoparticles: A green, efficient, and solvent-free protocol

Esmaiel Eidi
, Mohamad Z. Kassaee^*
, Zahra Nasresfahani
, Peter T. Cummings

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A practical and efficient method is developed for efficient synthesis of quinazoline derivatives through condensation reaction of 2-aminoaryl ketone, an aldehyde, and ammonium acetate, over magnetic Fe3O4@SiO2-PrNH2-Fe3+ NPs as a recyclable nanocatalyst, under solvent-free conditions. The as-prepared nanocatalyst was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). Mild conditions, easy work up, high purity of the products, recyclability, readily availability, nontoxicity, economical, and environmental-friendly nature of the iron catalyst are the attractive features of this methodology.

Original language	English
Article number	e4573
Journal	Applied Organometallic Chemistry
Volume	32
Issue number	12
DOIs	https://doi.org/10.1002/aoc.4573
Publication status	Published - Dec 2018

Keywords

Iron catalyst
Magnetic nanoparticles
Quinazoline
Recyclable
Solvent-free

ASJC Scopus subject areas

General Chemistry
Inorganic Chemistry

Access to Document

10.1002/aoc.4573

Cite this

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title = "Synthesis of quinazolines over recyclable Fe3O4@SiO2-PrNH2-Fe3+ nanoparticles: A green, efficient, and solvent-free protocol",

abstract = "A practical and efficient method is developed for efficient synthesis of quinazoline derivatives through condensation reaction of 2-aminoaryl ketone, an aldehyde, and ammonium acetate, over magnetic Fe3O4@SiO2-PrNH2-Fe3+ NPs as a recyclable nanocatalyst, under solvent-free conditions. The as-prepared nanocatalyst was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). Mild conditions, easy work up, high purity of the products, recyclability, readily availability, nontoxicity, economical, and environmental-friendly nature of the iron catalyst are the attractive features of this methodology.",

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T1 - Synthesis of quinazolines over recyclable Fe3O4@SiO2-PrNH2-Fe3+ nanoparticles: A green, efficient, and solvent-free protocol

AU - Eidi, Esmaiel

AU - Kassaee, Mohamad Z.

AU - Nasresfahani, Zahra

AU - Cummings, Peter T.

PY - 2018/12

Y1 - 2018/12

N2 - A practical and efficient method is developed for efficient synthesis of quinazoline derivatives through condensation reaction of 2-aminoaryl ketone, an aldehyde, and ammonium acetate, over magnetic Fe3O4@SiO2-PrNH2-Fe3+ NPs as a recyclable nanocatalyst, under solvent-free conditions. The as-prepared nanocatalyst was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). Mild conditions, easy work up, high purity of the products, recyclability, readily availability, nontoxicity, economical, and environmental-friendly nature of the iron catalyst are the attractive features of this methodology.

AB - A practical and efficient method is developed for efficient synthesis of quinazoline derivatives through condensation reaction of 2-aminoaryl ketone, an aldehyde, and ammonium acetate, over magnetic Fe3O4@SiO2-PrNH2-Fe3+ NPs as a recyclable nanocatalyst, under solvent-free conditions. The as-prepared nanocatalyst was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). Mild conditions, easy work up, high purity of the products, recyclability, readily availability, nontoxicity, economical, and environmental-friendly nature of the iron catalyst are the attractive features of this methodology.

KW - Iron catalyst

KW - Magnetic nanoparticles

KW - Quinazoline

KW - Recyclable

KW - Solvent-free

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DO - 10.1002/aoc.4573

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