Synthesis of novel hydroperoxy-substituted 1,2,4,5-tetroxepanes and 1,2,4,5-tetroxocanes

Yuji Nonami, Yoshihiro Ushigoe, Araki Masuyama, Masatomo Nojima, Kevin J. McCullough

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Ozonolysis of vinyl ether 1 in the presence of unsaturated hydroperoxides 3 gave the corresponding unsaturated hydroperoxy peracetals 4, which in turn reacted with ozone in acetic acid to give the novel hydroperoxy-substituted cyclic peroxides containing two peroxide groups in the ring. The structure of 1-methyl-4-phenyl-2,3,5,6-tetroxocanyl hydroperoxide 12 was unambiguously determined by the X-ray analysis.

Original languageEnglish
Pages (from-to)6597-6600
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number36
DOIs
Publication statusPublished - Sep 1998

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