TY - JOUR
T1 - Synthesis of nido-Diplatinacarborane and closo-Diplatinacarborane Complexes by
Direct Insertion; Crystal and Molecular Structures of closo-2,3-[(Et3P)2]2-1,2,3,6-CPt2CB5H7,
nido-μ-(4,8)-[(Me3P)2Pt]-8,8-[(Me3P)2]-7,8,10-CPtCB8H10
and nido-8,8-[(Me3P)2]-7,8,10-CPtCB8H10
AU - Barker, Geoffrey K.
AU - Green, Michael
AU - Spencer, John L.
AU - Stone, F. Gordon A.
AU - Taylor, Brian F.
AU - Welch, Alan J.
PY - 1975
Y1 - 1975
N2 - fullt title: Synthesis of nido- and closo-diplatinacarborane complexes by direct insertion; crystal and molecular structures of closo-2,3-[(Et3P) 2]2-1,2,3,6-CPt2CB5H7, nido-μ (4,8)-[(Me3P)2Pt]-8,8-[(Me3P) 2]-7,8,10-CPtCB8H10 and nido-8,8-[(Me 3)2]-7,8,10-CPtCB8H10. Reaction of closo-2,4-C2B5H7 with [Pt(styrene)-(PEt3)2] affords closo-2,3-[(Et 3P)2]2-1,2,3,6 -CPt2CB 5H7, whereas [Pt(1,5-C8H12)(PMe 3)2] and 1,6-C2B8H10 gives nido-μ(4,8)-[(Me3P)2]- 7,8,10-CPtCB 8H10 which on treatment with activated charcoal affords, nido-8,8-[(Me3P)2] -7,8,10-CPtCB8H 10; the structural identity of the complexes was established by X-ray crystallography.
AB - fullt title: Synthesis of nido- and closo-diplatinacarborane complexes by direct insertion; crystal and molecular structures of closo-2,3-[(Et3P) 2]2-1,2,3,6-CPt2CB5H7, nido-μ (4,8)-[(Me3P)2Pt]-8,8-[(Me3P) 2]-7,8,10-CPtCB8H10 and nido-8,8-[(Me 3)2]-7,8,10-CPtCB8H10. Reaction of closo-2,4-C2B5H7 with [Pt(styrene)-(PEt3)2] affords closo-2,3-[(Et 3P)2]2-1,2,3,6 -CPt2CB 5H7, whereas [Pt(1,5-C8H12)(PMe 3)2] and 1,6-C2B8H10 gives nido-μ(4,8)-[(Me3P)2]- 7,8,10-CPtCB 8H10 which on treatment with activated charcoal affords, nido-8,8-[(Me3P)2] -7,8,10-CPtCB8H 10; the structural identity of the complexes was established by X-ray crystallography.
UR - http://www.scopus.com/inward/record.url?scp=51149214600&partnerID=8YFLogxK
U2 - 10.1039/C39750000804
DO - 10.1039/C39750000804
M3 - Article
SN - 0022-4936
SP - 804
EP - 805
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 19
ER -