Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands:  X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)

Yassin N. Al-Obaidi; Michael Green; Nicholas D. White; Jean Marie Bassett; Alan J. Welch

doi:10.1039/C39810000494

Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)

Yassin N. Al-Obaidi^*
, Michael Green
, Nicholas D. White
, Jean Marie Bassett
, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Reaction of [Rh ₃ (μ-CO) ₃ (η ⁵ -C ₉ H ₇ ) ₃ ] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh ₂ (μ-CO) (μ-1,3-diene) (η ⁵ -C ₉ H ₇ ) ₂ ]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.

Original language	English
Pages (from-to)	494-496
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39810000494
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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Al-Obaidi, Y. N., Green, M., White, N. D., Bassett, J. M., & Welch, A. J. (1981). Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh). Journal of the Chemical Society, Chemical Communications, (10), 494-496. https://doi.org/10.1039/C39810000494

@article{bedcaf9160d24e78bbd82aa6062b26dc,

title = "Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)",

abstract = " Reaction of [Rh 3 (μ-CO) 3 (η 5 -C 9 H 7 ) 3 ] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh 2 (μ-CO) (μ-1,3-diene) (η 5 -C 9 H 7 ) 2 ]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems. ",

author = "Al-Obaidi, \{Yassin N.\} and Michael Green and White, \{Nicholas D.\} and Bassett, \{Jean Marie\} and Welch, \{Alan J.\}",

year = "1981",

doi = "10.1039/C39810000494",

language = "English",

pages = "494--496",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "10",

}

Al-Obaidi, YN, Green, M, White, ND, Bassett, JM & Welch, AJ 1981, 'Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)', Journal of the Chemical Society, Chemical Communications, no. 10, pp. 494-496. https://doi.org/10.1039/C39810000494

Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh). / Al-Obaidi, Yassin N.; Green, Michael; White, Nicholas D. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 10, 1981, p. 494-496.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)

AU - Al-Obaidi, Yassin N.

AU - Green, Michael

AU - White, Nicholas D.

AU - Bassett, Jean Marie

AU - Welch, Alan J.

PY - 1981

Y1 - 1981

N2 - Reaction of [Rh 3 (μ-CO) 3 (η 5 -C 9 H 7 ) 3 ] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh 2 (μ-CO) (μ-1,3-diene) (η 5 -C 9 H 7 ) 2 ]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.

AB - Reaction of [Rh 3 (μ-CO) 3 (η 5 -C 9 H 7 ) 3 ] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh 2 (μ-CO) (μ-1,3-diene) (η 5 -C 9 H 7 ) 2 ]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.

UR - https://www.scopus.com/pages/publications/37049092946

U2 - 10.1039/C39810000494

DO - 10.1039/C39810000494

M3 - Article

AN - SCOPUS:37049092946

SN - 0022-4936

SP - 494

EP - 496

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)

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