TY - JOUR
T1 - Synthesis of Di-rhodium Complexes Containing σ-cis-Bridging 1,3-Diene Ligands: X-Ray Crystal and Molecular Structure of μ-(η4-Cyclohexa-1,3-diene)-μ-carbonyl-bis-(η5-indenyl)dirhodium(Rh-Rh)
AU - Al-Obaidi, Yassin N.
AU - Green, Michael
AU - White, Nicholas D.
AU - Bassett, Jean Marie
AU - Welch, Alan J.
PY - 1981
Y1 - 1981
N2 -
Reaction of [Rh
3
(μ-CO)
3
(η
5
-C
9
H
7
)
3
] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh
2
(μ-CO) (μ-1,3-diene) (η
5
-C
9
H
7
)
2
]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.
AB -
Reaction of [Rh
3
(μ-CO)
3
(η
5
-C
9
H
7
)
3
] with buta-1,3-diene, trans-penta-1,3-diene, isoprene, trans, trans-hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh
2
(μ-CO) (μ-1,3-diene) (η
5
-C
9
H
7
)
2
]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.
UR - http://www.scopus.com/inward/record.url?scp=37049092946&partnerID=8YFLogxK
U2 - 10.1039/C39810000494
DO - 10.1039/C39810000494
M3 - Article
AN - SCOPUS:37049092946
SN - 0022-4936
SP - 494
EP - 496
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 10
ER -