Synthesis of C-glycofuranosides by the stereoselective reduction of hemiacetals

Eguzkiñe Calzada, Catherine A. Clarke, Christine Roussin-Bouchard, Richard H. Wightman

Research output: Contribution to journalArticle

Abstract

Reaction of protected glycofuranolactones with organolithium reagents and reduction of the resultant hemiacetals with triethylsilane-boron trifluoride gives a stereocontrolled route to C-glycofuranosides, with hydride delivery occurring cis- to an adjacent oxygen function.

Original languageEnglish
Pages (from-to)517-518
Number of pages2
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number5
Publication statusPublished - 1995

Fingerprint Dive into the research topics of 'Synthesis of C-glycofuranosides by the stereoselective reduction of hemiacetals'. Together they form a unique fingerprint.

  • Cite this

    Calzada, E., Clarke, C. A., Roussin-Bouchard, C., & Wightman, R. H. (1995). Synthesis of C-glycofuranosides by the stereoselective reduction of hemiacetals. Journal of the Chemical Society, Perkin Transactions 1, (5), 517-518.