Synthesis of a Large, Shape-flexible, Solvatomorphic Porous Organic Cage

Baiyang Teng, Marc A. Little*, Tom Hasell, Samantha Y. Chong, Kim E. Jelfs, Rob Clowes, Michael E. Briggs, Andrew I. Cooper*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Porous organic cages have emerged over the last 10 years as a subclass of functional microporous materials. However, among all of the organic cages reported, large multicomponent organic cages with 20 components or more are still rare. Here, we present an [8 + 12] porous organic imine cage, CC20, which has an apparent surface area up to 1752 m2 g-1, depending on the crystallization and activation conditions. The cage is solvatomorphic and displays distinct geometrical cage structures, caused by crystal-packing effects, in its crystal structures. This indicates that larger cages can display a certain range of shape flexibility in the solid state, while remaining shape persistent and porous.
Original languageEnglish
Pages (from-to)3647-3651
Number of pages5
JournalCrystal Growth and Design
Volume19
Issue number7
DOIs
Publication statusPublished - 15 May 2019

Keywords

  • Crystal structure
  • Crystals
  • Molecular structure
  • Solvates
  • Solvents

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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