Synthesis, characterisation and magnetic properties of a one-dimensional iron(II) coordination polymer

M. Lucia Romero, Paz Vaqueiro

Research output: Contribution to journalArticle

Abstract

A new iron(II) coordination polymer, [FeCl2(NC7H 9)2(N2C12H12)], has been synthesized under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction. This material crystallizes in the monoclinic space group C2/c, with a = 11.2850(6), b = 13.8925(7), c = 17.0988(9) Å and ß = 94.300(3)° (Z = 4). The crystal structure consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated. The infinite polymer chains are packed into a three-dimensional structure through C-H?Cl interactions. Magnetic susceptibility measurements reveal the existence of weak antiferromagnetic interactions between the iron(II) ions. The effective magnetic moment, µ eff = 5.33 µ B, is consistent with a high-spin iron(II) configuration. Graphical Abstract: The crystal structure of the coordination polymer [FeCl2(NC 7H9)2(N2C12H 12)] consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated. © 2010 Springer Science+Business Media, LLC.

Original languageEnglish
Pages (from-to)601-605
Number of pages5
JournalJournal of Chemical Crystallography
Volume41
Issue number5
DOIs
Publication statusPublished - May 2011

Keywords

  • Crystal structure
  • Iron(II) coordination polymer
  • Magnetic behaviour
  • Solvothermal synthesis

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