Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex: {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n

Nirmal Kumar Karan; Samiran Mitra; Georgina Rosair; David J. Jenkins; K. M Abdul Malik

doi:10.1016/S1387-7003(01)00316-1

Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex: {[Ba₂(phen)₄(H₂O)₆Fe (CN)₆]·Cl·2 (phen)·3H₂O}_n

Nirmal Kumar Karan, Samiran Mitra, Georgina Rosair, David J. Jenkins, K. M Abdul Malik

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba₂(phen)₄(H₂O)₆Fe (CN)₆]·Cl·2 (phen)·3H₂O}_n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba₂(phen)₄(H₂O)₆] units are bridged through two trans CN groups of [Fe(CN)₆]^3- ion, which results in the formation of a zig-zag polymeric chain. In each [Ba₂(phen)₄(H₂O)₆] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together. © 2001 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	712-715
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	4
Issue number	12
DOIs	https://doi.org/10.1016/S1387-7003(01)00316-1
Publication status	Published - 2001

Keywords

Barium
Crystal structure
Cyano-bridge
Iron
Phenanthroline

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10.1016/S1387-7003(01)00316-1

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@article{cd653cf2d68247e79c87a227be7b9309,

title = "Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex: {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n",

abstract = "A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba2(phen)4(H2O)6] units are bridged through two trans CN groups of [Fe(CN)6]3- ion, which results in the formation of a zig-zag polymeric chain. In each [Ba2(phen)4(H2O)6] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together. {\textcopyright} 2001 Elsevier Science B.V. All rights reserved.",

keywords = "Barium, Crystal structure, Cyano-bridge, Iron, Phenanthroline",

author = "Karan, {Nirmal Kumar} and Samiran Mitra and Georgina Rosair and Jenkins, {David J.} and Malik, {K. M Abdul}",

year = "2001",

doi = "10.1016/S1387-7003(01)00316-1",

language = "English",

volume = "4",

pages = "712--715",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "12",

}

Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex: {[Ba₂(phen)₄(H₂O)₆Fe (CN)₆]·Cl·2 (phen)·3H₂O}_n. / Karan, Nirmal Kumar; Mitra, Samiran; Rosair, Georgina et al.
In: Inorganic Chemistry Communications, Vol. 4, No. 12, 2001, p. 712-715.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex

T2 - {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n

AU - Karan, Nirmal Kumar

AU - Mitra, Samiran

AU - Rosair, Georgina

AU - Jenkins, David J.

AU - Malik, K. M Abdul

PY - 2001

Y1 - 2001

N2 - A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba2(phen)4(H2O)6] units are bridged through two trans CN groups of [Fe(CN)6]3- ion, which results in the formation of a zig-zag polymeric chain. In each [Ba2(phen)4(H2O)6] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together. © 2001 Elsevier Science B.V. All rights reserved.

AB - A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba2(phen)4(H2O)6Fe (CN)6]·Cl·2 (phen)·3H2O}n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba2(phen)4(H2O)6] units are bridged through two trans CN groups of [Fe(CN)6]3- ion, which results in the formation of a zig-zag polymeric chain. In each [Ba2(phen)4(H2O)6] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together. © 2001 Elsevier Science B.V. All rights reserved.

KW - Barium

KW - Crystal structure

KW - Cyano-bridge

KW - Iron

KW - Phenanthroline

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DO - 10.1016/S1387-7003(01)00316-1

M3 - Article

SN - 1387-7003

VL - 4

SP - 712

EP - 715

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium-iron complex: {[Ba₂(phen)₄(H₂O)₆Fe (CN)₆]·Cl·2 (phen)·3H₂O}_n

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