Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C σ-bond

Sambuddha Banerjee; Soma Sen; Samiran Mitra; Corrado Rizzoli; Georgina M. Rosair

doi:10.1039/b718343g

Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C σ-bond

Sambuddha Banerjee, Soma Sen, Samiran Mitra, Corrado Rizzoli, Georgina M. Rosair

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The aerial oxidation of cobalt(ii) salt, in a methanolic solution, containing a hydrazone ligand, (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) benzohydrazide (condensation product of benzoyl acetone and benzhydrazide, LH₂) leads to the coupling of two such ligand units through the formation of a rather long C-C bond [1.601(6) Å] giving rise to a dinuclear Co (iii) hydrazone complex, [Co₂(L)₂(L') ₂]•0.25H₂O (L' = C-C coupled hydrazone ligand). The structure of the complex has been determined by X-ray crystallography and IR, UV-Vis spectroscopy and elemental analysis have characterized the complex. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1783-1786
Number of pages	4
Journal	Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/b718343g
Publication status	Published - 2008

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title = "Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C σ-bond",

abstract = "The aerial oxidation of cobalt(ii) salt, in a methanolic solution, containing a hydrazone ligand, (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) benzohydrazide (condensation product of benzoyl acetone and benzhydrazide, LH2) leads to the coupling of two such ligand units through the formation of a rather long C-C bond [1.601(6) {\AA}] giving rise to a dinuclear Co (iii) hydrazone complex, [Co2(L)2(L') 2]•0.25H2O (L' = C-C coupled hydrazone ligand). The structure of the complex has been determined by X-ray crystallography and IR, UV-Vis spectroscopy and elemental analysis have characterized the complex. {\textcopyright} The Royal Society of Chemistry.",

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T1 - Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C σ-bond

AU - Banerjee, Sambuddha

AU - Sen, Soma

AU - Mitra, Samiran

AU - Rizzoli, Corrado

AU - Rosair, Georgina M.

PY - 2008

Y1 - 2008

N2 - The aerial oxidation of cobalt(ii) salt, in a methanolic solution, containing a hydrazone ligand, (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) benzohydrazide (condensation product of benzoyl acetone and benzhydrazide, LH2) leads to the coupling of two such ligand units through the formation of a rather long C-C bond [1.601(6) Å] giving rise to a dinuclear Co (iii) hydrazone complex, [Co2(L)2(L') 2]•0.25H2O (L' = C-C coupled hydrazone ligand). The structure of the complex has been determined by X-ray crystallography and IR, UV-Vis spectroscopy and elemental analysis have characterized the complex. © The Royal Society of Chemistry.

AB - The aerial oxidation of cobalt(ii) salt, in a methanolic solution, containing a hydrazone ligand, (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) benzohydrazide (condensation product of benzoyl acetone and benzhydrazide, LH2) leads to the coupling of two such ligand units through the formation of a rather long C-C bond [1.601(6) Å] giving rise to a dinuclear Co (iii) hydrazone complex, [Co2(L)2(L') 2]•0.25H2O (L' = C-C coupled hydrazone ligand). The structure of the complex has been determined by X-ray crystallography and IR, UV-Vis spectroscopy and elemental analysis have characterized the complex. © The Royal Society of Chemistry.

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U2 - 10.1039/b718343g

DO - 10.1039/b718343g

M3 - Article

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 13

ER -

Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C σ-bond

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