Synthesis and reactivity of [Pd(C N)(C6F5)(NCMe)] (C N = dimethylbenzylamine-C2,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu4)[{Pd(8-quinolylmethyl-C,N)(C6F5)}2(μ-Cl)]

J. Forniés; R. Navarro; V. Sicilia; F. Martinez; A. J. Welch

doi:10.1016/0022-328X(91)83212-M

Synthesis and reactivity of [Pd(C N)(C₆F₅)(NCMe)] (C N = dimethylbenzylamine-C²,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu₄)[{Pd(8-quinolylmethyl-C,N)(C₆F₅)}₂(μ-Cl)]

J. Forniés^*, R. Navarro, V. Sicilia, F. Martinez, A. J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The reaction between [Pd(C N)(THF)₂ClO₄ (THF = tetrahydrofuran; C N = dimethylbenzylamineC²,N, dmba; 8-quinolylmethyl-C,N, 8-mq) and (NBu₄)₂[M(C₆F₅)₄] (M = Pd, Pt) in the presence of L (L = NCMe, PPh₃, PPhMe₂) gave the neutral derivatives [Pd(C N)(C₆F₅)L], whereas reaction of [Pd(C N)(NCMe)₂]ClO₄ with (NBu₄)₂[M(C₆F₅)₄] (M = Pd, Pt), gave the corresponding species [Pd(C N)(C₆F₅)(NCMe)] (C N = dmba (1), 8-mq (6)). 1 and 6 reacted with phosphines to yield [Pd(C N)(C₆F₅)(PR₃)] (PR₃ = PPh₃ (2, 7); PPhMe₂, C N = dmba (3), and with (NBu₄)Br to yield (NBu₄)[Pd(C N)(C₆F₅)X] (X = Br, C N = dmba (4), 8-mq (8); and 9 (X = Cl, C N = 8-mq) was obtained by treatment of 8 with AgCl. The binuclear derivatives with a single bridging halide ligand (NBu₄)[{Pd(C N)(C₆F₅)}₂(μ-X)] (X = Br, C N = dmba (5), 8-mq (10); X = Cl, C N = 8-mq (11)) were obtained by reacting 1 or 6 with 4, 8 or 9, respectively. The molecular structure of 11 was established by a single crystal X-ray study.

Original language	English
Pages (from-to)	425-437
Number of pages	13
Journal	Journal of Organometallic Chemistry
Volume	408
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)83212-M
Publication status	Published - 21 May 1991

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{c5be55a131e549ed912cf5a4f35ad2ee,

title = "Synthesis and reactivity of [Pd(C N)(C6F5)(NCMe)] (C N = dimethylbenzylamine-C2,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu4)[{Pd(8-quinolylmethyl-C,N)(C6F5)}2(μ-Cl)]",

abstract = "The reaction between [Pd(C N)(THF)2ClO4 (THF = tetrahydrofuran; C N = dimethylbenzylamineC2,N, dmba; 8-quinolylmethyl-C,N, 8-mq) and (NBu4)2[M(C6F5)4] (M = Pd, Pt) in the presence of L (L = NCMe, PPh3, PPhMe2) gave the neutral derivatives [Pd(C N)(C6F5)L], whereas reaction of [Pd(C N)(NCMe)2]ClO4 with (NBu4)2[M(C6F5)4] (M = Pd, Pt), gave the corresponding species [Pd(C N)(C6F5)(NCMe)] (C N = dmba (1), 8-mq (6)). 1 and 6 reacted with phosphines to yield [Pd(C N)(C6F5)(PR3)] (PR3 = PPh3 (2, 7); PPhMe2, C N = dmba (3), and with (NBu4)Br to yield (NBu4)[Pd(C N)(C6F5)X] (X = Br, C N = dmba (4), 8-mq (8); and 9 (X = Cl, C N = 8-mq) was obtained by treatment of 8 with AgCl. The binuclear derivatives with a single bridging halide ligand (NBu4)[{Pd(C N)(C6F5)}2(μ-X)] (X = Br, C N = dmba (5), 8-mq (10); X = Cl, C N = 8-mq (11)) were obtained by reacting 1 or 6 with 4, 8 or 9, respectively. The molecular structure of 11 was established by a single crystal X-ray study.",

author = "J. Forni{\'e}s and R. Navarro and V. Sicilia and F. Martinez and Welch, {A. J.}",

year = "1991",

month = may,

day = "21",

doi = "10.1016/0022-328X(91)83212-M",

language = "English",

volume = "408",

pages = "425--437",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "3",

}

Synthesis and reactivity of [Pd(C N)(C₆F₅)(NCMe)] (C N = dimethylbenzylamine-C²,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu₄)[{Pd(8-quinolylmethyl-C,N)(C₆F₅)}₂(μ-Cl)]. / Forniés, J.; Navarro, R.; Sicilia, V. et al.

In: Journal of Organometallic Chemistry, Vol. 408, No. 3, 21.05.1991, p. 425-437.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and reactivity of [Pd(C N)(C6F5)(NCMe)] (C N = dimethylbenzylamine-C2,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu4)[{Pd(8-quinolylmethyl-C,N)(C6F5)}2(μ-Cl)]

AU - Forniés, J.

AU - Navarro, R.

AU - Sicilia, V.

AU - Martinez, F.

AU - Welch, A. J.

PY - 1991/5/21

Y1 - 1991/5/21

N2 - The reaction between [Pd(C N)(THF)2ClO4 (THF = tetrahydrofuran; C N = dimethylbenzylamineC2,N, dmba; 8-quinolylmethyl-C,N, 8-mq) and (NBu4)2[M(C6F5)4] (M = Pd, Pt) in the presence of L (L = NCMe, PPh3, PPhMe2) gave the neutral derivatives [Pd(C N)(C6F5)L], whereas reaction of [Pd(C N)(NCMe)2]ClO4 with (NBu4)2[M(C6F5)4] (M = Pd, Pt), gave the corresponding species [Pd(C N)(C6F5)(NCMe)] (C N = dmba (1), 8-mq (6)). 1 and 6 reacted with phosphines to yield [Pd(C N)(C6F5)(PR3)] (PR3 = PPh3 (2, 7); PPhMe2, C N = dmba (3), and with (NBu4)Br to yield (NBu4)[Pd(C N)(C6F5)X] (X = Br, C N = dmba (4), 8-mq (8); and 9 (X = Cl, C N = 8-mq) was obtained by treatment of 8 with AgCl. The binuclear derivatives with a single bridging halide ligand (NBu4)[{Pd(C N)(C6F5)}2(μ-X)] (X = Br, C N = dmba (5), 8-mq (10); X = Cl, C N = 8-mq (11)) were obtained by reacting 1 or 6 with 4, 8 or 9, respectively. The molecular structure of 11 was established by a single crystal X-ray study.

AB - The reaction between [Pd(C N)(THF)2ClO4 (THF = tetrahydrofuran; C N = dimethylbenzylamineC2,N, dmba; 8-quinolylmethyl-C,N, 8-mq) and (NBu4)2[M(C6F5)4] (M = Pd, Pt) in the presence of L (L = NCMe, PPh3, PPhMe2) gave the neutral derivatives [Pd(C N)(C6F5)L], whereas reaction of [Pd(C N)(NCMe)2]ClO4 with (NBu4)2[M(C6F5)4] (M = Pd, Pt), gave the corresponding species [Pd(C N)(C6F5)(NCMe)] (C N = dmba (1), 8-mq (6)). 1 and 6 reacted with phosphines to yield [Pd(C N)(C6F5)(PR3)] (PR3 = PPh3 (2, 7); PPhMe2, C N = dmba (3), and with (NBu4)Br to yield (NBu4)[Pd(C N)(C6F5)X] (X = Br, C N = dmba (4), 8-mq (8); and 9 (X = Cl, C N = 8-mq) was obtained by treatment of 8 with AgCl. The binuclear derivatives with a single bridging halide ligand (NBu4)[{Pd(C N)(C6F5)}2(μ-X)] (X = Br, C N = dmba (5), 8-mq (10); X = Cl, C N = 8-mq (11)) were obtained by reacting 1 or 6 with 4, 8 or 9, respectively. The molecular structure of 11 was established by a single crystal X-ray study.

UR - http://www.scopus.com/inward/record.url?scp=0010842452&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(91)83212-M

DO - 10.1016/0022-328X(91)83212-M

M3 - Article

AN - SCOPUS:0010842452

SN - 0022-328X

VL - 408

SP - 425

EP - 437

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Synthesis and reactivity of [Pd(C N)(C₆F₅)(NCMe)] (C N = dimethylbenzylamine-C²,N; 8-quinolylmethyl-C,N. Crystal structure of (NBu₄)[{Pd(8-quinolylmethyl-C,N)(C₆F₅)}₂(μ-Cl)]

Abstract

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