TY - JOUR
T1 - Synthesis and reactivity of an unsymmetrically substituted 16-membered macrocyclic complex of nickel(II) and the crystal structure of its acyclic precursor, (3-acetyl-10-methyl-5,9-diazatrideca-3,8-diene-2,12-dionato)nickel(II)
AU - Cameron, James H.
AU - McCullough, Kevin J.
AU - Scott, Elinor L.
PY - 1996/10
Y1 - 1996/10
N2 - The synthesis of the new unsymmetrically substituted 16-membered macrocyclic complex, (3-acetyl-2,10,12-trimethyl-1, 5, 9, 13-tetraazacyclohexadeca-1, 3, 9, 11-tetra-enato)-NiII, by template-controlled macrocyclization is reported. This complex has a single nucleophilic site available to react with electrophilic reagents. The crystal structure of the acyclic precursor, (3-acetyl-10-methyl-5,9-diazatrideca-3,8-diene-2,12-dionato)NiII shows that in the solid state it exists as a pair of enantiomers, arising from the presence of two possible skew boat conformations adopted by the six-membered saturated metallochelate ring present in the molecule. © 1996 Chapman & Hall.
AB - The synthesis of the new unsymmetrically substituted 16-membered macrocyclic complex, (3-acetyl-2,10,12-trimethyl-1, 5, 9, 13-tetraazacyclohexadeca-1, 3, 9, 11-tetra-enato)-NiII, by template-controlled macrocyclization is reported. This complex has a single nucleophilic site available to react with electrophilic reagents. The crystal structure of the acyclic precursor, (3-acetyl-10-methyl-5,9-diazatrideca-3,8-diene-2,12-dionato)NiII shows that in the solid state it exists as a pair of enantiomers, arising from the presence of two possible skew boat conformations adopted by the six-membered saturated metallochelate ring present in the molecule. © 1996 Chapman & Hall.
UR - http://www.scopus.com/inward/record.url?scp=0003710624&partnerID=8YFLogxK
M3 - Article
SN - 1572-901X
VL - 21
SP - 451
EP - 456
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 5
ER -