Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co2(ButNC)8] and [Ru(Ph3P)(Bu tNC)4]

Geoffrey K. Barker; Anita M. R. Galas; Michael Green; Judith A. K. Howard; F. Gordon A. Stone; Terence W. Turney; Alan J. Welch; Peter Woodward

doi:10.1039/C39770000256

Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co₂(Bu^tNC)₈] and [Ru(Ph₃P)(Bu ^tNC)₄]

Geoffrey K. Barker, Anita M. R. Galas, Michael Green^*, Judith A. K. Howard, F. Gordon A. Stone, Terence W. Turney, Alan J. Welch, Peter Woodward

^*Corresponding author for this work

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Abstract

Reduction of [Co(Bu^tNC)₅PF₆ with K-Hg in tetrahydrofuran affords the complex Co₂(Bu^tNC) ₈], and similarly trans-[RuCl₂(Bu^tNC) ₄] with Bu^tNC, trans-[RuCl₂(Bu ^tNC)₄] with Ph₃P and Bu^tNC, and trans-[RuCl₂-(PrⁱNC)₄] with PrⁱNC give [Ru(Bu^tNC)₅], [Ru(Bu^tNC) ₄(Ph₃P)], and [Ru₂(PrⁱNC) ₉], respectively; the structures of [Co₂(Bu ^tNC)₈] and [Ru(Bu^tNC)₄(Ph ₃P)] are established by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	256-258
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39770000256
Publication status	Published - 1977

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Galas, A. M. R., Green, M., Howard, J. A. K., Stone, F. G. A., Turney, T. W., Welch, A. J., & Woodward, P. (1977). Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co₂(Bu^tNC)₈] and [Ru(Ph₃P)(Bu ^tNC)₄]. Journal of the Chemical Society, Chemical Communications, (8), 256-258. https://doi.org/10.1039/C39770000256

@article{c7a49e3e1b3c47308405769efbd2f75e,

title = "Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co2(ButNC)8] and [Ru(Ph3P)(Bu tNC)4]",

abstract = "Reduction of [Co(ButNC)5PF6 with K-Hg in tetrahydrofuran affords the complex Co2(ButNC) 8], and similarly trans-[RuCl2(ButNC) 4] with ButNC, trans-[RuCl2(Bu tNC)4] with Ph3P and ButNC, and trans-[RuCl2-(PriNC)4] with PriNC give [Ru(ButNC)5], [Ru(ButNC) 4(Ph3P)], and [Ru2(PriNC) 9], respectively; the structures of [Co2(Bu tNC)8] and [Ru(ButNC)4(Ph 3P)] are established by single crystal X-ray diffraction.",

author = "Barker, {Geoffrey K.} and Galas, {Anita M. R.} and Michael Green and Howard, {Judith A. K.} and Stone, {F. Gordon A.} and Turney, {Terence W.} and Welch, {Alan J.} and Peter Woodward",

year = "1977",

doi = "10.1039/C39770000256",

language = "English",

pages = "256--258",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

}

Barker, GK, Galas, AMR, Green, M, Howard, JAK, Stone, FGA, Turney, TW, Welch, AJ & Woodward, P 1977, 'Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co₂(Bu^tNC)₈] and [Ru(Ph₃P)(Bu ^tNC)₄]', Journal of the Chemical Society, Chemical Communications, no. 8, pp. 256-258. https://doi.org/10.1039/C39770000256

Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co₂(Bu^tNC)₈] and [Ru(Ph₃P)(Bu ^tNC)₄]. / Barker, Geoffrey K.; Galas, Anita M. R.; Green, Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 1977, p. 256-258.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co2(ButNC)8] and [Ru(Ph3P)(Bu tNC)4]

AU - Barker, Geoffrey K.

AU - Galas, Anita M. R.

AU - Green, Michael

AU - Howard, Judith A. K.

AU - Stone, F. Gordon A.

AU - Turney, Terence W.

AU - Welch, Alan J.

AU - Woodward, Peter

PY - 1977

Y1 - 1977

N2 - Reduction of [Co(ButNC)5PF6 with K-Hg in tetrahydrofuran affords the complex Co2(ButNC) 8], and similarly trans-[RuCl2(ButNC) 4] with ButNC, trans-[RuCl2(Bu tNC)4] with Ph3P and ButNC, and trans-[RuCl2-(PriNC)4] with PriNC give [Ru(ButNC)5], [Ru(ButNC) 4(Ph3P)], and [Ru2(PriNC) 9], respectively; the structures of [Co2(Bu tNC)8] and [Ru(ButNC)4(Ph 3P)] are established by single crystal X-ray diffraction.

AB - Reduction of [Co(ButNC)5PF6 with K-Hg in tetrahydrofuran affords the complex Co2(ButNC) 8], and similarly trans-[RuCl2(ButNC) 4] with ButNC, trans-[RuCl2(Bu tNC)4] with Ph3P and ButNC, and trans-[RuCl2-(PriNC)4] with PriNC give [Ru(ButNC)5], [Ru(ButNC) 4(Ph3P)], and [Ru2(PriNC) 9], respectively; the structures of [Co2(Bu tNC)8] and [Ru(ButNC)4(Ph 3P)] are established by single crystal X-ray diffraction.

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U2 - 10.1039/C39770000256

DO - 10.1039/C39770000256

M3 - Article

AN - SCOPUS:37049106799

SN - 0022-4936

SP - 256

EP - 258

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Synthesis and reactions of octakis(t-butyl isocyanide)dicobalt and pentakis(t-butyl isocyanide)ruthenium; X-ray crystal and molecular structures of [Co₂(Bu^tNC)₈] and [Ru(Ph₃P)(Bu ^tNC)₄]

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