Synthesis and molecular structures of nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10,11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10]; evidence for a multiple metal–metal bond in a dimetallacarbaborane

Geoffrey K. Barker; Norman R. Godfrey; Michael Green; Hans E. Parge; F. Gordon A. Stone; Alan J. Welch

doi:10.1039/C39830000277

Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane

Geoffrey K. Barker^*, Norman R. Godfrey, Michael Green, Hans E. Parge, F. Gordon A. Stone, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

From nido-5,6-C₂B₈H₁₂, the compounds nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_{10, 11}-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀] have been synthesised, and their structure identities established by X-ray crystallography.

Original language	English
Pages (from-to)	277-279
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39830000277
Publication status	Published - 1983

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Godfrey, N. R., Green, M., Parge, H. E., Stone, F. G. A., & Welch, A. J. (1983). Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane. Journal of the Chemical Society, Chemical Communications, (6), 277-279. https://doi.org/10.1039/C39830000277

Barker, Geoffrey K. ; Godfrey, Norman R. ; Green, Michael et al. / Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane. In: Journal of the Chemical Society, Chemical Communications. 1983 ; No. 6. pp. 277-279.

@article{aa75cd395b80424cb657513ac73cb44b,

title = "Synthesis and molecular structures of nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10,11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10]; evidence for a multiple metal–metal bond in a dimetallacarbaborane",

abstract = "From nido-5,6-C2B8H12, the compounds nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10, 11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10] have been synthesised, and their structure identities established by X-ray crystallography.",

author = "Barker, {Geoffrey K.} and Godfrey, {Norman R.} and Michael Green and Parge, {Hans E.} and Stone, {F. Gordon A.} and Welch, {Alan J.}",

year = "1983",

doi = "10.1039/C39830000277",

language = "English",

pages = "277--279",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "6",

}

Barker, GK, Godfrey, NR, Green, M, Parge, HE, Stone, FGA & Welch, AJ 1983, 'Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane', Journal of the Chemical Society, Chemical Communications, no. 6, pp. 277-279. https://doi.org/10.1039/C39830000277

Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane. / Barker, Geoffrey K.; Godfrey, Norman R.; Green, Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 6, 1983, p. 277-279.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and molecular structures of nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10,11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10]; evidence for a multiple metal–metal bond in a dimetallacarbaborane

AU - Barker, Geoffrey K.

AU - Godfrey, Norman R.

AU - Green, Michael

AU - Parge, Hans E.

AU - Stone, F. Gordon A.

AU - Welch, Alan J.

PY - 1983

Y1 - 1983

N2 - From nido-5,6-C2B8H12, the compounds nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10, 11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10] have been synthesised, and their structure identities established by X-ray crystallography.

AB - From nido-5,6-C2B8H12, the compounds nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10, 11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10] have been synthesised, and their structure identities established by X-ray crystallography.

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U2 - 10.1039/C39830000277

DO - 10.1039/C39830000277

M3 - Article

AN - SCOPUS:51149202093

SN - 0022-4936

SP - 277

EP - 279

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

Barker GK, Godfrey NR, Green M, Parge HE, Stone FGA, Welch AJ. Synthesis and molecular structures of nido-[9-(η-C₅H₅)-7,8,9-C₂NiB₈H₁₁], nido-[9-(η-C₅H₅)-µ_10,11-(Ph₃PAu)-7,8,9-C₂NiB₈H₁₀], and closo-[1,3-(η-C₅H₅)₂-1,2,3,4-CrCCrCB₈H₁₀]; evidence for a multiple metal–metal bond in a dimetallacarbaborane. Journal of the Chemical Society, Chemical Communications. 1983;(6):277-279. doi: 10.1039/C39830000277