TY - JOUR
T1 - Synthesis and magnetic study of new μ-oxalato dinuclear copper (II) complexes
AU - Mukherjee, Partha Sarathi
AU - Maji, Tapas Kumar
AU - Koner, Subratanath
AU - Rosair, Georgina
AU - Chaudhuri, Nirmalendu Ray
PY - 2001/5
Y1 - 2001/5
N2 - Three new µ-oxalato dinuclear copper(II) complexes [L(H2O)CuOxCu(H2O)L](ClO4)2 [L = 4-(2-aminoethyl)morpholine (aem), (1), 1-(2-aminoethyl)piperidine (ampp), (2) and 1-(2-aminoethyl)pyrrolidine (ampy), (3)] have been synthesized and characterized by X-ray single crystal analysis (1), IR, thermal analysis and magnetic measurements. Low temperature magnetic measurements of these complexes show the existence of strong antiferromagnetic interaction between the copper(II) ions.
AB - Three new µ-oxalato dinuclear copper(II) complexes [L(H2O)CuOxCu(H2O)L](ClO4)2 [L = 4-(2-aminoethyl)morpholine (aem), (1), 1-(2-aminoethyl)piperidine (ampp), (2) and 1-(2-aminoethyl)pyrrolidine (ampy), (3)] have been synthesized and characterized by X-ray single crystal analysis (1), IR, thermal analysis and magnetic measurements. Low temperature magnetic measurements of these complexes show the existence of strong antiferromagnetic interaction between the copper(II) ions.
UR - http://www.scopus.com/inward/record.url?scp=0346311387&partnerID=8YFLogxK
M3 - Article
SN - 0376-4710
VL - 40
SP - 451
EP - 455
JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
IS - 5
ER -