Synthesis and magnetic study of new μ-oxalato dinuclear copper (II) complexes

Partha Sarathi Mukherjee, Tapas Kumar Maji, Subratanath Koner, Georgina Rosair, Nirmalendu Ray Chaudhuri

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Three new µ-oxalato dinuclear copper(II) complexes [L(H2O)CuOxCu(H2O)L](ClO4)2 [L = 4-(2-aminoethyl)morpholine (aem), (1), 1-(2-aminoethyl)piperidine (ampp), (2) and 1-(2-aminoethyl)pyrrolidine (ampy), (3)] have been synthesized and characterized by X-ray single crystal analysis (1), IR, thermal analysis and magnetic measurements. Low temperature magnetic measurements of these complexes show the existence of strong antiferromagnetic interaction between the copper(II) ions.

Original languageEnglish
Pages (from-to)451-455
Number of pages5
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume40
Issue number5
Publication statusPublished - May 2001

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