Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

Leslie D. Field; Hsiu L. Li; Scott J. Dalgarno; Paul Jensen; Ruaraidh D. McIntosh

doi:10.1021/ic102519f

Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

Leslie D. Field^*, Hsiu L. Li, Scott J. Dalgarno, Paul Jensen, Ruaraidh D. McIntosh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

Original language	English
Pages (from-to)	5468-5476
Number of pages	9
Journal	Inorganic Chemistry
Volume	50
Issue number	12
DOIs	https://doi.org/10.1021/ic102519f
Publication status	Published - 20 Jun 2011

Keywords

MOLECULAR-HYDROGEN COMPLEXES
PARENT AMIDO COMPLEX
CATALYTIC-REDUCTION
BIS(HYDRAZINE) COMPLEXES
SULFUR LIGANDS
N-N BOND
CARBON-MONOXIDE
HYDRAZIDO(1-) COMPLEXES
STRUCTURAL-CHARACTERIZATION
TRANSITION-METAL-COMPLEXES

Access to Document

10.1021/ic102519f

Cite this

@article{087105740d6e4c01b67922cca40deca5,

title = "Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes",

abstract = "Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.",

keywords = "MOLECULAR-HYDROGEN COMPLEXES, PARENT AMIDO COMPLEX, CATALYTIC-REDUCTION, BIS(HYDRAZINE) COMPLEXES, SULFUR LIGANDS, N-N BOND, CARBON-MONOXIDE, HYDRAZIDO(1-) COMPLEXES, STRUCTURAL-CHARACTERIZATION, TRANSITION-METAL-COMPLEXES",

author = "Field, {Leslie D.} and Li, {Hsiu L.} and Dalgarno, {Scott J.} and Paul Jensen and McIntosh, {Ruaraidh D.}",

year = "2011",

month = jun,

day = "20",

doi = "10.1021/ic102519f",

language = "English",

volume = "50",

pages = "5468--5476",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

AU - Field, Leslie D.

AU - Li, Hsiu L.

AU - Dalgarno, Scott J.

AU - Jensen, Paul

AU - McIntosh, Ruaraidh D.

PY - 2011/6/20

Y1 - 2011/6/20

N2 - Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

AB - Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

KW - MOLECULAR-HYDROGEN COMPLEXES

KW - PARENT AMIDO COMPLEX

KW - CATALYTIC-REDUCTION

KW - BIS(HYDRAZINE) COMPLEXES

KW - SULFUR LIGANDS

KW - N-N BOND

KW - CARBON-MONOXIDE

KW - HYDRAZIDO(1-) COMPLEXES

KW - STRUCTURAL-CHARACTERIZATION

KW - TRANSITION-METAL-COMPLEXES

U2 - 10.1021/ic102519f

DO - 10.1021/ic102519f

M3 - Article

SN - 0020-1669

VL - 50

SP - 5468

EP - 5476

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

Abstract

Keywords

Access to Document

Fingerprint

Cite this