Synthesis and characterization of inorganic-organic hybrid gallium selenides

Sarah J. Ewing; Paz Vaqueiro

doi:10.1021/ic5011314

Synthesis and characterization of inorganic-organic hybrid gallium selenides

Sarah J. Ewing, Paz Vaqueiro^*

^*Corresponding author for this work

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Two semiconducting hybrid gallium selenides, [Ga₆Se ₉(C₆H₁₄N₂)₄][H ₂O] (1) and [C₆H₁₄N₂][Ga ₄Se₆(C₆H₁₄N₂) ₂] (2), were prepared using a solvothermal method in the presence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is covalently bonded to gallium. In 1, the organic amine acts as a monodentate and a bidentate ligand, while in 2, bidentate and uncoordinated 1,2-DACH molecules coexist.

Original language	English
Pages (from-to)	8845-8847
Number of pages	3
Journal	Inorganic Chemistry
Volume	53
Issue number	17
DOIs	https://doi.org/10.1021/ic5011314
Publication status	Published - 2014

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic5011314

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title = "Synthesis and characterization of inorganic-organic hybrid gallium selenides",

abstract = "Two semiconducting hybrid gallium selenides, [Ga6Se 9(C6H14N2)4][H 2O] (1) and [C6H14N2][Ga 4Se6(C6H14N2) 2] (2), were prepared using a solvothermal method in the presence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is covalently bonded to gallium. In 1, the organic amine acts as a monodentate and a bidentate ligand, while in 2, bidentate and uncoordinated 1,2-DACH molecules coexist.",

author = "Ewing, {Sarah J.} and Paz Vaqueiro",

year = "2014",

doi = "10.1021/ic5011314",

language = "English",

volume = "53",

pages = "8845--8847",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis and characterization of inorganic-organic hybrid gallium selenides

AU - Ewing, Sarah J.

AU - Vaqueiro, Paz

PY - 2014

Y1 - 2014

N2 - Two semiconducting hybrid gallium selenides, [Ga6Se 9(C6H14N2)4][H 2O] (1) and [C6H14N2][Ga 4Se6(C6H14N2) 2] (2), were prepared using a solvothermal method in the presence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is covalently bonded to gallium. In 1, the organic amine acts as a monodentate and a bidentate ligand, while in 2, bidentate and uncoordinated 1,2-DACH molecules coexist.

AB - Two semiconducting hybrid gallium selenides, [Ga6Se 9(C6H14N2)4][H 2O] (1) and [C6H14N2][Ga 4Se6(C6H14N2) 2] (2), were prepared using a solvothermal method in the presence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is covalently bonded to gallium. In 1, the organic amine acts as a monodentate and a bidentate ligand, while in 2, bidentate and uncoordinated 1,2-DACH molecules coexist.

U2 - 10.1021/ic5011314

DO - 10.1021/ic5011314

M3 - Article

C2 - 25113435

AN - SCOPUS:84906856800

SN - 0020-1669

VL - 53

SP - 8845

EP - 8847

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Synthesis and characterization of inorganic-organic hybrid gallium selenides

Abstract

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