Synthesis and characterization of inorganic-organic hybrid gallium selenides

Sarah J. Ewing, Paz Vaqueiro

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Two semiconducting hybrid gallium selenides, [Ga6Se 9(C6H14N2)4][H 2O] (1) and [C6H14N2][Ga 4Se6(C6H14N2) 2] (2), were prepared using a solvothermal method in the presence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is covalently bonded to gallium. In 1, the organic amine acts as a monodentate and a bidentate ligand, while in 2, bidentate and uncoordinated 1,2-DACH molecules coexist.

Original languageEnglish
Pages (from-to)8845-8847
Number of pages3
JournalInorganic Chemistry
Volume53
Issue number17
DOIs
Publication statusPublished - 2014

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

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