Synthesis and characterisation of a triple cluster of gold and boron

Andrew J. Wynd; Suzanne E. Robins; Dorothy A. Welch; Alan J. Welch

doi:10.1039/c39850000819

Synthesis and characterisation of a triple cluster of gold and boron

Andrew J. Wynd, Suzanne E. Robins, Dorothy A. Welch, Alan J. Welch^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Reaction of B₁₀H₁₄ with Et₃PAuMe affords the triple cluster [(H₁₂B₁₀Au)(AuPEt₃)₄(AuB₁₀H₁₂)] and with Cy₃PAuMe (CY = cyclohexyl) the substituted complex [Cy₃PAu(B₁₀H₁₃)] is isolated; a mechanism for the formation of the triple cluster is proposed.

Original language	English
Pages (from-to)	819-820
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/c39850000819
Publication status	Published - 1985

ASJC Scopus subject areas

Molecular Medicine

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@article{ba16dca1e83343e5a09845a8f721bdc3,

title = "Synthesis and characterisation of a triple cluster of gold and boron",

abstract = "Reaction of B10H14 with Et3PAuMe affords the triple cluster [(H12B10Au)(AuPEt3)4(AuB10H12)] and with Cy3PAuMe (CY = cyclohexyl) the substituted complex [Cy3PAu(B10H13)] is isolated; a mechanism for the formation of the triple cluster is proposed.",

author = "Wynd, \{Andrew J.\} and Robins, \{Suzanne E.\} and Welch, \{Dorothy A.\} and Welch, \{Alan J.\}",

year = "1985",

doi = "10.1039/c39850000819",

language = "English",

pages = "819--820",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis and characterisation of a triple cluster of gold and boron

AU - Wynd, Andrew J.

AU - Robins, Suzanne E.

AU - Welch, Dorothy A.

AU - Welch, Alan J.

PY - 1985

Y1 - 1985

N2 - Reaction of B10H14 with Et3PAuMe affords the triple cluster [(H12B10Au)(AuPEt3)4(AuB10H12)] and with Cy3PAuMe (CY = cyclohexyl) the substituted complex [Cy3PAu(B10H13)] is isolated; a mechanism for the formation of the triple cluster is proposed.

AB - Reaction of B10H14 with Et3PAuMe affords the triple cluster [(H12B10Au)(AuPEt3)4(AuB10H12)] and with Cy3PAuMe (CY = cyclohexyl) the substituted complex [Cy3PAu(B10H13)] is isolated; a mechanism for the formation of the triple cluster is proposed.

UR - https://www.scopus.com/pages/publications/37049105131

U2 - 10.1039/c39850000819

DO - 10.1039/c39850000819

M3 - Article

AN - SCOPUS:37049105131

SN - 0022-4936

SP - 819

EP - 820

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

Synthesis and characterisation of a triple cluster of gold and boron

Abstract

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