Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

Jonathan P. H. Charmant, Mairi F. Haddow, F. Ekkehardt Hahn, Dennis Heitmann, Roland Fröhlich, Stephen M Mansell, Christopher A. Russell, Duncan F. Wass

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36 Citations (Scopus)

Abstract

Cyclic diamino plumbylenes derived from saturated heterocycles are obtained from deprotonation of diamines and subsequent reaction with PbCl2, or by reaction of a suitable diamine with Pb[N(SiMe3)2]2. Single crystal X-ray studies have been used to probe the solid state structures of a range of these complexes and have shown the fine balance between monomer and dimer formation which is related to the bulk of the organic group attached to the nitrogen atoms. Dimerisation is also shown to effect structural changes within the core of the heterocyclic plumbylene.
Original languageEnglish
Pages (from-to)6055-6059
Number of pages5
JournalDalton Transactions
Issue number43
DOIs
Publication statusPublished - 21 Nov 2008

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    Charmant, J. P. H., Haddow, M. F., Hahn, F. E., Heitmann, D., Fröhlich, R., Mansell, S. M., Russell, C. A., & Wass, D. F. (2008). Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes. Dalton Transactions, (43), 6055-6059. https://doi.org/10.1039/b808717b